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Structure, Raman and infrared spectroscopic properties of new nonlinear optical material Na3VO2B6O11

文献类型：期刊论文

作者Zhang, Ji1; Dou, Renqin2; Zhang, Deming2; Zhang, Qingli2; Yin, Shaotang2
刊名JOURNAL OF MOLECULAR STRUCTURE
出版日期2016-08-15
卷号1118期号:无页码:378-382
关键词Na3vo2b6o11 Crystal Raman Spectra Ir Spectra Phonon
DOI10.1016/j.molstruc.2016.03.086
文献子类Article
英文摘要In this paper we report on the structure of Na3VO2B6O11 (NVBO) single crystals which were investigated by XRD, polarized Raman spectra in the range from 10 to 1600 cm(-1) and infrared spectrum (IR) in the range from 100 to 1600 cm(-1). Factor group analysis has been used to study the full vibrational representation of the crystal. More than 120 phonon modes have been obtained, which are related to B-O and V-O vibration in the trigonal planar BO3 triangle groups and tetrahedral BO4/VO4 groups. The high frequency bands located at 1300-1415 cm(-1) are assigned to stretching modes of the trigonal planar BO3 groups. Moreover, intense Raman modes located at 631 cm(-1) is related to BO3 bending vibration as well. The weak band at 1158 cm(-1) (A(1) mode) and strong band at 431 cm(-1) (A(1) mode) are attributed to asymmetric stretching and bending vibration mode of tetrahedral BO4 groups respectively. The vibrational band at 765-738 cm(-1) in the Raman spectra of NVBO crystal maybe related to the breathing vibration of the boroxol ring consisting of two BO4 tetrahedra. In addition, we assigned the intense band 900 (A(1) mode) and 831 cm(-1) (132 mode) are relative to the v(1) symmetric stretching vibration of VO4 tetrahedra. And the middle intense band at 382 (A(1) mode) and 385 (A(2) mode) are due to O-V-O vibration in VO4 tetrahedra. (C) 2016 Published by Elsevier B.V.
WOS关键词CRYSTAL-STRUCTURE ; GLASSES ; SPECTRA ; LI2B4O7 ; LIB3O5 ; GROWTH ; IR
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000377828700048
资助机构Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/30871]  
专题合肥物质科学研究院_中科院安徽光学精密机械研究所
作者单位1.Anhui Xin Hua Univ, Hefei 230088, Peoples R China
2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Ji,Dou, Renqin,Zhang, Deming,et al. Structure, Raman and infrared spectroscopic properties of new nonlinear optical material Na3VO2B6O11[J]. JOURNAL OF MOLECULAR STRUCTURE,2016,1118(无):378-382.
APA Zhang, Ji,Dou, Renqin,Zhang, Deming,Zhang, Qingli,&Yin, Shaotang.(2016).Structure, Raman and infrared spectroscopic properties of new nonlinear optical material Na3VO2B6O11.JOURNAL OF MOLECULAR STRUCTURE,1118(无),378-382.
MLA Zhang, Ji,et al."Structure, Raman and infrared spectroscopic properties of new nonlinear optical material Na3VO2B6O11".JOURNAL OF MOLECULAR STRUCTURE 1118.无(2016):378-382.

入库方式： OAI收割

来源：合肥物质科学研究院

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