ELECTROCATALYSIS AT A MICRODISK ELECTRODE MODIFIED WITH A REDOX SPECIES
文献类型:期刊论文
作者 | DONG SJ ; CHE GL |
刊名 | journal of electroanalytical chemistry
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出版日期 | 1991 |
卷号 | 309期号:1-2页码:103-114 |
关键词 | CROSS-EXCHANGE REACTIONS POLY-PARA-NITROSTYRENE STEADY-STATE METHOD ION MERCURY SYSTEM ELECTROCHEMICAL REACTIONS GRAPHITE-ELECTRODES KINETICS FILMS COATINGS MICROELECTRODES |
ISSN号 | 0022-0728 |
通讯作者 | dong sj |
中文摘要 | the current equation of the electrocatalytic reaction at a microdisk electrode modified with redox species has been described and verified experimentally. there exists a linear relationship between plateau limiting current and the radius of the microdisk electrode for a catalytic process. the influence of the dimensions of the microdisk electrode on catalytic efficiency is discussed. the polyvinylferrocene (pvfc)-modified microdisk electrode prepared by the coating method was taken as a typical example, on which the electrocatalytic oxidation of ascorbic acid could be studied. the catalytic reaction rate constants were determined as an average value of 1.5 x 10(-7) cm3/mol s by this method, and are consistent with those obtained at a conventional electrode. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2011-03-03 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/38417] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | DONG SJ,CHE GL. ELECTROCATALYSIS AT A MICRODISK ELECTRODE MODIFIED WITH A REDOX SPECIES[J]. journal of electroanalytical chemistry,1991,309(1-2):103-114. |
APA | DONG SJ,&CHE GL.(1991).ELECTROCATALYSIS AT A MICRODISK ELECTRODE MODIFIED WITH A REDOX SPECIES.journal of electroanalytical chemistry,309(1-2),103-114. |
MLA | DONG SJ,et al."ELECTROCATALYSIS AT A MICRODISK ELECTRODE MODIFIED WITH A REDOX SPECIES".journal of electroanalytical chemistry 309.1-2(1991):103-114. |
入库方式: OAI收割
来源:长春应用化学研究所
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