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Facile preparation of amino functionalized graphene oxide decorated with Fe3O4 nanoparticles for the adsorption of Cr(VI)

文献类型:期刊论文

作者Zhao, Donglin1; Gao, Xuan1; Wu, Changnian1; Xie, Rong1; Feng, Shaojie1; Chen, Changlun2
刊名APPLIED SURFACE SCIENCE
出版日期2016-10-30
卷号384期号:页码:1-9
关键词Fe3o4/graphene Oxide Composite Adsorption Cr(Vi)
DOI10.1016/j.apsusc.2016.05.022
文献子类Article
英文摘要A novel ternary magnetic composite consisting of graphene oxide (GO), diethylenetriamine and Fe3O4 nanoparticles (AMGO) were synthesized by a facile one-step reaction route and characterized. The AMGO was applied as a magnetic adsorbent for the Cr(VI) removal from aqueous solutions and the magnetic separation process only took 40 s. The maximum adsorption capacity of the AMGO for Cr(VI) was 123.4 mg/g, displaying a high efficiency for the removal of Cr(VI), which was much higher than that of MGO. The removal process was pH dependence, endothermic and spontaneous. The pseudo-second-order model described well the adsorption kinetic data and the Langmuir isotherm model fitted the experimental data better than the Freundlich isotherm model. XPS analysis revealed that the Cr(VI) was reduced to the low-toxicity Cr(III) during the adsorption process. Both the Cr(VI) adsorption and subsequent reduction of adsorbed Cr(VI) to Cr(III) contributed to the Cr(VI) removal. In addition, the excellent reproducibility indicate that the AMGO may be a promising adsorption material for the separation and preconcentration of Cr(VI) ions from aqueous solutions in environmental pollution cleanup. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词ZERO-VALENT IRON ; FAST CHROMIUM REMOVAL ; AQUEOUS-SOLUTION ; MAGNETIC CYCLODEXTRIN ; ACTIVATED CARBON ; WASTE-WATER ; HEAVY-METAL ; NANOCOMPOSITE ; COMPOSITES ; NANOSHEETS
WOS研究方向Chemistry ; Materials Science ; Physics
语种英语
WOS记录号WOS:000378560900001
资助机构National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; National Natural Science Foundation of China(21377005 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 21477133 ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134) ; 41273134)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/21766]  
专题合肥物质科学研究院_中科院等离子体物理研究所
作者单位1.Anhui Jianzhu Univ, Key Lab Funct Mol Design & Interface Proc, Hefei 230601, Peoples R China
2.Chinese Acad Sci, Inst Plasma Phys, POB 1126, Hefei 230031, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Donglin,Gao, Xuan,Wu, Changnian,et al. Facile preparation of amino functionalized graphene oxide decorated with Fe3O4 nanoparticles for the adsorption of Cr(VI)[J]. APPLIED SURFACE SCIENCE,2016,384(无):1-9.
APA Zhao, Donglin,Gao, Xuan,Wu, Changnian,Xie, Rong,Feng, Shaojie,&Chen, Changlun.(2016).Facile preparation of amino functionalized graphene oxide decorated with Fe3O4 nanoparticles for the adsorption of Cr(VI).APPLIED SURFACE SCIENCE,384(无),1-9.
MLA Zhao, Donglin,et al."Facile preparation of amino functionalized graphene oxide decorated with Fe3O4 nanoparticles for the adsorption of Cr(VI)".APPLIED SURFACE SCIENCE 384.无(2016):1-9.

入库方式: OAI收割

来源:合肥物质科学研究院

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