中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Removal of radiocobalt ions from aqueous solutions by natural halloysite nanotubes

文献类型:期刊论文

作者Li, Jie1,2; Wen, Feng1; Pan, Lisha1; Liu, Zhengjie3; Dong, Yunhui3
刊名JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
出版日期2013
卷号295期号:1页码:431-438
关键词Natural Halloysite Nanotubes Radiocobalt Removal Thermodynamic Data
DOI10.1007/s10967-012-1823-x
文献子类Article
英文摘要In this study, natural halloysite nanotubes (HNTs) were applied to remove radiocobalt from wastewaters under various environmental parameters such as contact time, pH, ionic strength, foreign ions and temperature by using batch technique. The results indicated that the sorption of Co(II) on HNTs was dependent on ionic strength at pH < 8.5 and independent of ionic strength at pH > 8.5. Langmuir and Freundlich models were applied to simulate the sorption isotherms of Co(II) at three different temperatures of 293, 313 and 333 K. Langmuir model fitted the sorption isotherms of Co(II) on HNTs better than Freundlich model. The thermodynamic parameters (Delta G (0), Delta S (0) and Delta H (0)) calculated from the temperature-dependent sorption isotherms manifested that the sorption of Co(II) on HNTs was an endothermic and spontaneous process. The sorption of Co(II) was dominated by outer-sphere surface complexation or ion exchange at low pH, whereas inner-sphere surface complexation or precipitation was the main sorption mechanism at high pH. The experimental results show that HNTs have good potentialities for cost-effective disposal of cobalt-bearing wastewaters.
WOS关键词MULTIWALLED CARBON NANOTUBES ; MX-80 BENTONITE ; SEQUESTRATION MECHANISMS ; MAGNETIC COMPOSITE ; FOREIGN IONS ; WASTE-WATER ; FULVIC-ACID ; HUMIC-ACID ; RICE HUSK ; ADSORPTION
WOS研究方向Chemistry ; Nuclear Science & Technology
语种英语
WOS记录号WOS:000312784200058
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/22199]  
专题合肥物质科学研究院_中科院等离子体物理研究所
作者单位1.Hainan Univ, Key Lab Adv Mat Trop Isl Resources, Minist Educ, Sch Mat & Chem Engn, Haikou 570228, Peoples R China
2.Chinese Acad Sci, Key Lab Novel Thin Film Solar Cells, Inst Plasma Phys, Hefei 230031, Peoples R China
3.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China
推荐引用方式
GB/T 7714
Li, Jie,Wen, Feng,Pan, Lisha,et al. Removal of radiocobalt ions from aqueous solutions by natural halloysite nanotubes[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2013,295(1):431-438.
APA Li, Jie,Wen, Feng,Pan, Lisha,Liu, Zhengjie,&Dong, Yunhui.(2013).Removal of radiocobalt ions from aqueous solutions by natural halloysite nanotubes.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,295(1),431-438.
MLA Li, Jie,et al."Removal of radiocobalt ions from aqueous solutions by natural halloysite nanotubes".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 295.1(2013):431-438.

入库方式: OAI收割

来源:合肥物质科学研究院

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