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  4. 中科院等离子体物理研究所
Kinetic and thermodynamic studies on the interaction of europium(III) and phosphate with gamma-Al2O3

文献类型：期刊论文

作者Xu, Huan1,2; Liu, Ge2; Li, Guang1,3; Ren, Xuemei2; Gong, Yu4; Chen, Xiaojun4; Tan, Xiaoli2
刊名JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
出版日期2017
卷号311期号:1页码:395-408
关键词Mutual Effects Thermodynamic Gamma-al2o3 Europium(Iii) Phosphate
DOI10.1007/s10967-016-4957-4
文献子类Article
英文摘要The temperature effect on the co-sequestration process receives little attention. Herein, kinetic and thermodynamic studies on the co-sequestration of Eu(III) and phosphate by gamma-Al2O3 were investigated by batch experiments. The standard thermodynamic parameters (a dagger H (0), a dagger S (0), and a dagger G (0)), the activation thermodynamic parameters (a dagger H (#), a dagger S (#), and a dagger G (#)), and the activation energy (E (A)) for the co-sequestration process were obtained. Based on E (A) and a dagger S (#) values, Eu(III) and phosphate co-sequestration is controlled by chemical reactions on gamma-Al2O3 and by an associative mechanism. This work highlights the temperature effect on the co-sequestration of Eu(III) and phosphate in a geological environment.
WOS关键词CARBON NANOTUBES ; ADSORPTION-KINETICS ; AQUEOUS-SOLUTION ; U(VI) SORPTION ; TEMPERATURE ; REMOVAL ; EU(III) ; ALUMINA ; SURFACE ; BATCH
WOS研究方向Chemistry ; Nuclear Science & Technology
语种英语
WOS记录号WOS:000392075200042
资助机构National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 91326202) ; 91326202) ; 91326202) ; 91326202) ; 91326202) ; 91326202) ; 91326202) ; 91326202) ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; National Natural Science Foundation of China(21307135 ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Chinese National Fusion Project for ITER(2013GB110004) ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Anhui Provincial Natural Science Foundation(1608085QB44 ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; Science Foundation of Institute of Plasma Physics, Chinese Academy of Sciences(DSJJ-13-YY01) ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 21225730 ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 1508085MB29) ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 41273134 ; 21377132 ; 21377132 ; 21377132 ; 21377132 ; 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源URL[http://ir.hfcas.ac.cn:8080/handle/334002/31663]  
专题合肥物质科学研究院_中科院等离子体物理研究所
作者单位1.Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
2.Chinese Acad Sci, Inst Plasma Phys, POB 1126, Hefei 230031, Peoples R China
3.Anhui Key Lab Informat Mat & Devices, Hefei 230601, Peoples R China
4.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Peoples R China
推荐引用方式
GB/T 7714		 Xu, Huan,Liu, Ge,Li, Guang,et al. Kinetic and thermodynamic studies on the interaction of europium(III) and phosphate with gamma-Al2O3[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017,311(1):395-408.
APA Xu, Huan.,Liu, Ge.,Li, Guang.,Ren, Xuemei.,Gong, Yu.,...&Tan, Xiaoli.(2017).Kinetic and thermodynamic studies on the interaction of europium(III) and phosphate with gamma-Al2O3.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,311(1),395-408.
MLA Xu, Huan,et al."Kinetic and thermodynamic studies on the interaction of europium(III) and phosphate with gamma-Al2O3".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 311.1(2017):395-408.

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来源：合肥物质科学研究院

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