MOLECULAR-WEIGHT DEPENDENCE OF THE GLASS-TRANSITION OF CYCLIC POLYSTYRENE
文献类型:期刊论文
| 作者 | LIU XJ ; CHEN DL ; HE ZD ; ZHANG H ; HU HZ |
| 刊名 | polymer communications
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| 出版日期 | 1991 |
| 卷号 | 32期号:4页码:123-125 |
| ISSN号 | 0263-6476 |
| 中文摘要 | the glass transition temperature (t(g)) of cyclic polystyrene was measured by differential scanning calorimetry. there was a marked difference in the glass transition behaviour between cyclic and linear polystyrene. in the low molecular weight region (m(n) < 5 x 10(3)), the t(g) of the cyclic polystyrene increased with decreasing m(n), contrary to that of linear polystyrene. with m(n) higher than 5 x 10(3), the t(g) of cyclic polystyrene increased with increasing m(n). the t(g) of cyclic and linear polystyrene approached the same constant value when the m(n) was high enough (m(n) > 10(5)). combining the results of specific volume, it is believed that the variation of t(g) with molecular weight does not depend only on free volume effects but that configurational entropy is also an important factor. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-03-03 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/38519] ![]() |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | LIU XJ,CHEN DL,HE ZD,et al. MOLECULAR-WEIGHT DEPENDENCE OF THE GLASS-TRANSITION OF CYCLIC POLYSTYRENE[J]. polymer communications,1991,32(4):123-125. |
| APA | LIU XJ,CHEN DL,HE ZD,ZHANG H,&HU HZ.(1991).MOLECULAR-WEIGHT DEPENDENCE OF THE GLASS-TRANSITION OF CYCLIC POLYSTYRENE.polymer communications,32(4),123-125. |
| MLA | LIU XJ,et al."MOLECULAR-WEIGHT DEPENDENCE OF THE GLASS-TRANSITION OF CYCLIC POLYSTYRENE".polymer communications 32.4(1991):123-125. |
入库方式: OAI收割
来源:长春应用化学研究所
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