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  2. 合肥物质科学研究院
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  4. 中科院安徽光学精密机械研究所
Pyrolysis of n-butane investigated using synchrotron threshold photoelectron photoion coincidence spectroscopy

文献类型：期刊论文

作者Tang, Xiaofeng1; Lin, Xiaoxiao1; Zhu, Yupeng1,2; Wu, Xiangkun2,3; Wen, Zuoying1,2; Zhang, Lidong4; Liu, Fuyi4; Gu, Xuejun1; Zhang, Weijun1,5
刊名RSC ADVANCES
出版日期2017
卷号7期号:46页码:28746-28753
DOI10.1039/c7ra03990e
文献子类Article
英文摘要We present here the coupling of a flash pyrolysis micro-reactor with threshold photoelectron photoion coincidence (TPEPICO) spectroscopy at Hefei synchrotron to investigate thermal decomposition of nbutane. Primary products in the pyrolysis were determined with TPEPICO time-of-flight mass spectra and mass-selected threshold photoelectron spectra (TPES). Vibrational structures in the TPES of the CH3, C2H5 and C3H6 products were observed and their ionization energies were measured and compared satisfactorily to literature data. Moreover, the potential energy surface involved in the decomposition was calculated by using high-level quantum chemistry and several transition states were recognized. Then the detailed mechanisms of the pyrolysis of n-butane have been discussed and revealed.
WOS关键词THERMAL-DECOMPOSITION ; COMBUSTION CHEMISTRY ; VUV PHOTOIONIZATION ; LOW-PRESSURE ; MASS ; RADICALS ; SPECTRUM ; MOLECULES ; ELECTRONS ; ISOBUTANE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000403012700021
资助机构National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Natural Science Foundation of China(91644109 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Research and Development Program of China(2016YFC0200300 ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; National Key Scientific Instruments and Equipment Development Program of China(2012YQ220113) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; Natural Science Foundation of Anhui Province(1608085MB35) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 91544105) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205) ; 2016YFC0202205)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/31948]  
专题合肥物质科学研究院_中科院安徽光学精密机械研究所
作者单位1.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Lab Atmospher Physicochem, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Grad Sch, Hefei 230026, Anhui, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem Phys, Hefei 230026, Peoples R China
4.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China
5.Univ Sci & Technol China, Sch Environm Sci & Optoelect Technol, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Tang, Xiaofeng,Lin, Xiaoxiao,Zhu, Yupeng,et al. Pyrolysis of n-butane investigated using synchrotron threshold photoelectron photoion coincidence spectroscopy[J]. RSC ADVANCES,2017,7(46):28746-28753.
APA Tang, Xiaofeng.,Lin, Xiaoxiao.,Zhu, Yupeng.,Wu, Xiangkun.,Wen, Zuoying.,...&Zhang, Weijun.(2017).Pyrolysis of n-butane investigated using synchrotron threshold photoelectron photoion coincidence spectroscopy.RSC ADVANCES,7(46),28746-28753.
MLA Tang, Xiaofeng,et al."Pyrolysis of n-butane investigated using synchrotron threshold photoelectron photoion coincidence spectroscopy".RSC ADVANCES 7.46(2017):28746-28753.

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来源：合肥物质科学研究院

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