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Hydrogen sulfide at high pressure: Change in stoichiometry

文献类型：期刊论文

作者Goncharov, Alexander F.1,2,3; Lobanov, Sergey S.2,4; Kruglov, Ivan5,6; Zhao, Xiao-Miao2,7,8; Chen, Xiao-Jia1,2,8; Oganov, Artem R.5,6,9,10,11,12; Konopkova, Zuzana13; Prakapenka, Vitali B.14
刊名PHYSICAL REVIEW B
出版日期2016-05-10
卷号93期号:17页码:1-14
DOI10.1103/PhysRevB.93.174105
文献子类Article
英文摘要Hydrogen sulfide (H2S) was studied by x-ray synchrotron diffraction and Raman spectroscopy up to 150 GPa at 180-295 K and by quantum-mechanical variable-composition evolutionary simulations. The experiments show that H2S becomes unstable with respect to formation of compounds with different structure and composition, including Cccm and a body-centered cubic like (R3m or Im-3m) H3S, the latter one predicted previously to show a record-high superconducting transition temperature, a T-c of 203 K. These experiments provide experimental ground for understanding of this record-high T-c. The experimental results are supported by theoretical structure searches that suggest the stability of H3S, H4S3, H5S8, H3S5, and HS2 compounds that have not been reported previously at elevated pressures.
WOS关键词CRYSTAL-STRUCTURE PREDICTION ; MOLECULAR DISSOCIATION ; INFRARED-SPECTROSCOPY ; PHASE-TRANSITIONS ; SUPERCONDUCTIVITY ; H2S ; METALLIZATION ; LITHIUM ; SULFUR ; SYSTEM
WOS研究方向Physics
语种英语
WOS记录号WOS:000375990600002
资助机构ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; ARO(W911NF-13-1-0231) ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; DARPA(W31P4Q1210008 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSF(EAR-1520648 ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; NSFC(21473211) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; National Science Foundation-Earth Sciences(EAR-1128799) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; Department of Energy-Geosciences(DE-FG02-94ER14466) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. 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S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences(DE-AC02-06CH11357) ; U. S. 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源URL[http://ir.hfcas.ac.cn:8080/handle/334002/22101]  
专题合肥物质科学研究院_中科院固体物理研究所
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
2.Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA
3.Univ Sci & Technol China, Hefei 230026, Peoples R China
4.SB RAS, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia
5.Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Region, Russia
6.All Russia Res Inst Automat, Moscow 127055, Russia
7.S China Univ Technol, Dept Phys, Guangzhou 510640, Guangdong, Peoples R China
8.Ctr High Pressure Sci & Technol Adv Res, Shanghai 201203, Peoples R China
9.Skolkovo Innovat Ctr, Skolkovo Inst Sci & Technol, Moscow 143026, Russia
10.SUNY Stony Brook, Dept Geosci, Ctr Mat Design, Stony Brook, NY 11794 USA
推荐引用方式
GB/T 7714		 Goncharov, Alexander F.,Lobanov, Sergey S.,Kruglov, Ivan,et al. Hydrogen sulfide at high pressure: Change in stoichiometry[J]. PHYSICAL REVIEW B,2016,93(17):1-14.
APA Goncharov, Alexander F..,Lobanov, Sergey S..,Kruglov, Ivan.,Zhao, Xiao-Miao.,Chen, Xiao-Jia.,...&Prakapenka, Vitali B..(2016).Hydrogen sulfide at high pressure: Change in stoichiometry.PHYSICAL REVIEW B,93(17),1-14.
MLA Goncharov, Alexander F.,et al."Hydrogen sulfide at high pressure: Change in stoichiometry".PHYSICAL REVIEW B 93.17(2016):1-14.

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来源：合肥物质科学研究院

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