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  4. 中科院固体物理研究所
Mono-cadmium vs Mono-mercury Doping of Au-25 Nanoclusters

文献类型：期刊论文

作者Yao, Chuanhao1; Lin, Yue-jian2; Yuan, Jinyun3; Liao, Lingwen1; Zhu, Min1; Weng, Lin-hong2; Yang, Jinlong3; Wu, Zhikun1
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
出版日期2015-12-16
卷号137期号:49页码:15350-15353
DOI10.1021/jacs.5b09627
文献子类Article
英文摘要Controlling the dopant type, number, and position in doped metal nanoclusters (nanoparticles) is crucial but challenging. In the work described herein, we successfully achieved the mono-cadmium doping of Au-25 nanoclusters, and revealed using X-ray crystallography in combination with theoretical calculations that one of the inner-shell gold atoms of Au-25 was replaced by a Cd atom. The doping mode is distinctly different from that of mono-mercury doping, where one of the outer-shell Au atoms was replaced by a Hg atom. Au24Cd is readily transformed to Au24Hg, while the reverse (transformation from Au24Hg to Au24Cd) is forbidden under the investigated conditions.
WOS关键词OXYGEN REDUCTION REACTION ; ANTI-GALVANIC REDUCTION ; RAY CRYSTAL-STRUCTURE ; GOLD NANOCLUSTERS ; PROTECTED GOLD ; SILVER NANOPARTICLES ; ELECTRONIC-STRUCTURE ; ALLOY NANOMOLECULES ; ATOMIC PRECISION ; CHARGE-STATE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000366874700004
资助机构National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; Hefei Science Center, CAS(2015HSC-UP003) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21401064) ; 21401064) ; 21401064) ; 21401064)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/30213]  
专题合肥物质科学研究院_中科院固体物理研究所
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanostruct, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
2.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Yao, Chuanhao,Lin, Yue-jian,Yuan, Jinyun,et al. Mono-cadmium vs Mono-mercury Doping of Au-25 Nanoclusters[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(49):15350-15353.
APA Yao, Chuanhao.,Lin, Yue-jian.,Yuan, Jinyun.,Liao, Lingwen.,Zhu, Min.,...&Wu, Zhikun.(2015).Mono-cadmium vs Mono-mercury Doping of Au-25 Nanoclusters.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(49),15350-15353.
MLA Yao, Chuanhao,et al."Mono-cadmium vs Mono-mercury Doping of Au-25 Nanoclusters".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.49(2015):15350-15353.

入库方式： OAI收割

来源：合肥物质科学研究院

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