Anomalous low-temperature heat capacity in antiperovskite compounds
文献类型:期刊论文
作者 | Guo, Xin-Ge1,2; Lin, Jian-Chao1![]() ![]() ![]() ![]() ![]() ![]() |
刊名 | CHINESE PHYSICS B
![]() |
出版日期 | 2017-02-01 |
卷号 | 26期号:2页码:1-5 |
关键词 | Low-temperature Heat Capacity Low-energy Phonon Modes Antiperovskite Compound Negative Thermal Expansion |
DOI | 10.1088/1674-1056/26/2/026501 |
文献子类 | Article |
英文摘要 | The low-temperature heat capacities are studied for antiperovskite compounds AXM(3) (A = Al, Ga, Cu, Ag, Sn, X = C, N, M = Mn, Fe, Co). A large peak in (C-gamma T)/T-3 versus T is observed for each of a total of 18 compounds investigated, indicating an existence of low-energy phonon mode unexpected by Debye T-3 law. Such a peak is insensitive to the external magnetic field up to 80 kOe (1 Oe = 79.5775 A.m(1)). For compounds with smaller lattice constant, the peak shifts towards higher temperatures with a reduction of peak height. This abnormal peak in (C-gamma T)/T-3 versus T of antiperovskite compound may result from the strongly dispersive acoustic branch due to the heavier A atoms and the optical-like mode from the dynamic rotation of XM6 octahedron. Such a low-energy phonon mode may not contribute negatively to the normal thermal expansion in AXM(3) compounds, while it is usually concomitant with negative thermal expansion in open-structure material (e.g., ZrW2O8, ScF3). |
WOS关键词 | NEGATIVE THERMAL-EXPANSION ; BOSON PEAK ; ORIGIN ; ZRW2O8 ; RESISTIVITY ; COEFFICIENT ; SPECTRUM ; GLASSES ; SCF3 |
WOS研究方向 | Physics |
语种 | 英语 |
WOS记录号 | WOS:000402249000001 |
资助机构 | National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Key Basic Research Program of China(2011CBA00111) ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; National Natural Science Foundation of China(51322105 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; U1632158 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301165 ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) ; 51301167) |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/31912] ![]() |
专题 | 合肥物质科学研究院_中科院固体物理研究所 |
作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Peoples R China 4.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Xin-Ge,Lin, Jian-Chao,Tong, Peng,et al. Anomalous low-temperature heat capacity in antiperovskite compounds[J]. CHINESE PHYSICS B,2017,26(2):1-5. |
APA | Guo, Xin-Ge.,Lin, Jian-Chao.,Tong, Peng.,Lin, Shuai.,Yang, Cheng.,...&Sun, Yu-Ping.(2017).Anomalous low-temperature heat capacity in antiperovskite compounds.CHINESE PHYSICS B,26(2),1-5. |
MLA | Guo, Xin-Ge,et al."Anomalous low-temperature heat capacity in antiperovskite compounds".CHINESE PHYSICS B 26.2(2017):1-5. |
入库方式: OAI收割
来源:合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。