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Visualization of exhaled hydrogen sulphide on test paper with an ultrasensitive and time-gated luminescent probe

文献类型：期刊论文

作者Zhang, Ruilong1,2,3; Liu, Shijiang1,2; Wang, Jianping1; Han, Guangmei1; Yang, Linlin1,2; Liu, Bianhua1,3; Guan, Guijian1; Zhang, Zhongping1,2,3,4
刊名ANALYST
出版日期2016
卷号141期号:16页码:4919-4925
DOI10.1039/c6an00830e
文献子类Article
英文摘要Luminescent chemosensors for hydrogen sulphide (H2S) are of great interest because of the close association of H2S with our health. However, current probes for H2S detection have problems such as low sensitivity/selectivity, poor aqueous-solubility or interference from background fluorescence. This study reports an ultrasensitive and time-gated "switch on" probe for detection of H2S, and its application in test paper for visualization of exhaled H2S. The complex probe is synthesized with a luminescent Tb3+ centre and three ligands of azido (-N-3) substituted pyridine-2,6-dicarboxylic acid, giving the probe high hydrophilicity and relatively fast reaction dynamics with H2S because there are three -N-3 groups in each molecule. The introduced -N-3 group as a strong electron-withdrawing moiety effectively changes the energy level of ligand via intramolecular charge transfer (ICT), and thus breaks the energy transferring from ligand to lanthanide ion, resulting in quenching of Tb3+ luminescence. On addition of H2S, the -N-3 group can be reduced to an amine group to break the process of ICT, and the luminescence of Tb3+ is recovered at a nanomolar sensitivity level. With a long lifetime of luminescence of Tb3+ centre (1.9 ms), use of a time-gated technique effectively eliminates the background fluorescence by delaying fluorescence collection for 0.1 ms. The test paper imprinted by the complex probe ink can visualize clearly the trace H2S gas exhaled by mice.
WOS关键词FLUORESCENT-PROBES ; LIVING CELLS ; LIVE CELLS ; COMPLEXES ; SYNTHASE ; DISEASE ; SENSORS ; WATER ; H2S
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000381413800012
资助机构National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; 21475135 ; 21475135 ; 21475135 ; 21475135 ; 1508085SQB200) ; 1508085SQB200) ; 1508085SQB200) ; 1508085SQB200) ; 21375131 ; 21375131 ; 21375131 ; 21375131 ; 21277145) ; 21277145) ; 21277145) ; 21277145) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; National Natural Science Foundation of China(21335006 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; Natural Science Foundation of Anhui Province(1408085MKL52 ; 21475135 ; 21475135 ; 21475135 ; 21475135 ; 1508085SQB200) ; 1508085SQB200) ; 1508085SQB200) ; 1508085SQB200) ; 21375131 ; 21375131 ; 21375131 ; 21375131 ; 21277145) ; 21277145) ; 21277145) ; 21277145)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/30832]  
专题合肥物质科学研究院_中科院合肥智能机械研究所
作者单位1.Chinese Acad Sci, Inst Intelligent Machines, Ctr Excellence Nanosci, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
3.Anhui Univ, Sch Chem & Chem Engn, Hefei 230601, Peoples R China
4.Chinese Acad Sci, State Key Lab Transducer Technol, Hefei 230031, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Ruilong,Liu, Shijiang,Wang, Jianping,et al. Visualization of exhaled hydrogen sulphide on test paper with an ultrasensitive and time-gated luminescent probe[J]. ANALYST,2016,141(16):4919-4925.
APA Zhang, Ruilong.,Liu, Shijiang.,Wang, Jianping.,Han, Guangmei.,Yang, Linlin.,...&Zhang, Zhongping.(2016).Visualization of exhaled hydrogen sulphide on test paper with an ultrasensitive and time-gated luminescent probe.ANALYST,141(16),4919-4925.
MLA Zhang, Ruilong,et al."Visualization of exhaled hydrogen sulphide on test paper with an ultrasensitive and time-gated luminescent probe".ANALYST 141.16(2016):4919-4925.

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来源：合肥物质科学研究院

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