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Dual-Colored Carbon Dot Ratiometric Fluorescent Test Paper Based on a Specific Spectral Energy Transfer for Semiquantitative Assay of Copper Ions

文献类型：期刊论文

作者Liu, Cui1,2; Ning, Dianhua1,2; Zhang, Cheng1,2; Liu, Zhengjie1,2; Zhang, Ruilong3; Zhao, Jun1; Zhao, Tingting1; Liu, Bianhua1; Zhang, Zhongping1,3
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2017-06-07
卷号9期号:22页码:18897-18903
关键词Carbon Dots Rationiettic Fluorescence Test Paper Energy Transfer Copper Ions
DOI10.1021/acsami.7b05827
文献子类Article
英文摘要Classical pH test papers are widely used to measure the acid base degree of media in a qualitative or semiquantitative manner. However; extension of portable and inexpensive methods to a wide range of analytes so as to eliminate the tediousness of instrumental assays remains unsuccessful. Here, we report a novel kind, of dual-colored carbon dot (CD) ratiometric fluorescent test paper for the semiquantitative assay of copper ions (Cu2+ by a dose sensitive color evolution. The preparation of the test paper is based on the following two interesting findings: on the one hand, residual p-phenylenediamine at the, surface of as synthesized red CDs (r-Cbs) efficiently binds CO2+ ions to produce a strong visible absorption that overlaps, the emission of blue CDs (b-CDs); on the other hand, the ions render the adsorption of small b-CDs onto the surface of larger r-CDs, through their dual-coordinating irteractions with: the surface ligands of both r-Cbs and b-CDs. These two mechanisms lead to a specific spectral energy transfer to quench the fluorescence of b-CDs with a sensitive detection limit of 8.82 nM Cu2+, whereas the red fluorescence of t-Cbs is unaffected as a stable internal standard. Ratiometric fluorescent test papers have been prepared using a mixture of r-CDs and b-CDs (1:7) ink by jetprinting on a piece of paper. With the addition of Cu2+ ions, the blue test paper produces a consecutive wide-colered evolution from blue to orange-red, with a dose-discerning ability as low as 25 nM.
WOS关键词QUANTUM DOTS ; SENSITIVE DETECTION ; ELECTRONIC-SPECTRA ; EMISSION ; CHEMODOSIMETER ; VISUALIZATION ; LUMINESCENCE ; CHROMOPHORES ; IMIDAZOLES ; RHODAMINE
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
WOS记录号WOS:000403136400056
资助机构National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; 21335006 ; 21335006 ; 21335006 ; 21335006 ; 21475135 ; 21475135 ; 21475135 ; 21475135 ; 21375131 ; 21375131 ; 21375131 ; 21375131 ; 21277145 ; 21277145 ; 21277145 ; 21277145 ; 21275145) ; 21275145) ; 21275145) ; 21275145) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; National Basic Research Program of China(2015CB932002) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; China-Singapore Joint Project(2015DFG92510) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; Science and Technology Service Network Initiative of Chinese Academy of China(KFJ-SW-STS-172) ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; National Natural Science Foundation of China(21275075 ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; Natural Science Foundation of Anhui Province(1608085QB32) ; 21335006 ; 21335006 ; 21335006 ; 21335006 ; 21475135 ; 21475135 ; 21475135 ; 21475135 ; 21375131 ; 21375131 ; 21375131 ; 21375131 ; 21277145 ; 21277145 ; 21277145 ; 21277145 ; 21275145) ; 21275145) ; 21275145) ; 21275145)
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/31878]  
专题合肥物质科学研究院_中科院合肥智能机械研究所
作者单位1.Chinese Acad Sci, Inst Machine Intelligence, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
3.Anhui Univ, Sch Chem & Chem Engn, Hefei 230601, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Cui,Ning, Dianhua,Zhang, Cheng,et al. Dual-Colored Carbon Dot Ratiometric Fluorescent Test Paper Based on a Specific Spectral Energy Transfer for Semiquantitative Assay of Copper Ions[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(22):18897-18903.
APA Liu, Cui.,Ning, Dianhua.,Zhang, Cheng.,Liu, Zhengjie.,Zhang, Ruilong.,...&Zhang, Zhongping.(2017).Dual-Colored Carbon Dot Ratiometric Fluorescent Test Paper Based on a Specific Spectral Energy Transfer for Semiquantitative Assay of Copper Ions.ACS APPLIED MATERIALS & INTERFACES,9(22),18897-18903.
MLA Liu, Cui,et al."Dual-Colored Carbon Dot Ratiometric Fluorescent Test Paper Based on a Specific Spectral Energy Transfer for Semiquantitative Assay of Copper Ions".ACS APPLIED MATERIALS & INTERFACES 9.22(2017):18897-18903.

入库方式： OAI收割

来源：合肥物质科学研究院

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