SAPO-34 synthesized with n-butylamine as a template and its catalytic application in the methanol amination reaction
文献类型：期刊论文
| 作者 | Qiao, Yuyan1,2; Wu, Pengfei1,2; Xiang, Xiao1,2; Yang, Miao1; Wang, Quanyi1; Tian, Peng1; Liu, Zhongmin1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 38期号:3页码:574-582 |
| 关键词 | Sapo-34 Molecular Sieve N-butylamine Primary Amine Synthesis High Temperature Methanol Amination |
| DOI | 10.1016/S1872-2067(17)62775-X |
| 英文摘要 | SAPO-34 was synthesized with n-butylamine (BA) as a template for the first time. Crystallization temperature and initial Si amount were important factors leading to successful syntheses. Lamellar AlPO-kanemite tends to form as the major phase or as an impurity of SAPO-34 at lower crystallization temperatures, though a higher initial Si amount may offer a positive effect on the crystallization of SAPO-34 that mitigates the low temperature. Higher temperature (240 degrees C) can effectively suppress the generation of lamellar materials and allow the synthesis of pure SAPO-34 with a wider range of Si incorporation. The crystallization processes at 200 and 240 degrees C were investigated and compared. We used the aminothermal method to synthesize SAPO-34-BA at 240 degrees C and also found n-propylamine is a suitable template for the synthesis of SAPO-34. The SAP0-34-BA products were characterized by many techniques. SAP0-34-BA has good thermal stability, crystallinity and porosity. BA remained intact in the crystals with similar to 1.8 BA molecule per chabazite cage. The catalytic performance of SAPO-34 was tested in the methanol amination reaction, which showed high methanol conversion and selectivity for methylamine plus dimethylamine under the conditions investigated, suggesting that this material is a good candidate for the synthesis of methylamines. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000400125100019 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152012]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiao, Yuyan,Wu, Pengfei,Xiang, Xiao,et al. SAPO-34 synthesized with n-butylamine as a template and its catalytic application in the methanol amination reaction[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(3):574-582. |
| APA | Qiao, Yuyan.,Wu, Pengfei.,Xiang, Xiao.,Yang, Miao.,Wang, Quanyi.,...&Liu, Zhongmin.(2017).SAPO-34 synthesized with n-butylamine as a template and its catalytic application in the methanol amination reaction.CHINESE JOURNAL OF CATALYSIS,38(3),574-582. |
| MLA | Qiao, Yuyan,et al."SAPO-34 synthesized with n-butylamine as a template and its catalytic application in the methanol amination reaction".CHINESE JOURNAL OF CATALYSIS 38.3(2017):574-582. |
入库方式： OAI收割
来源：大连化学物理研究所
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