Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6
文献类型：期刊论文
| 作者 | Yuan, Bo1,2; Zhang, Bao1,2; Wang, Zhiliang1,2; Lu, Shengmei1; Li, Jun1; Liu, Yan1; Li, Can1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 38期号:3页码:440-446 |
| 关键词 | Flower-like Bi2wo6 Toluene Oxidation Benzaldehyde Cocatalyst Palladium Nanoparticle |
| DOI | 10.1016/S1872-2067(17)62757-8 |
| 英文摘要 | The selective oxidation of toluene and its derivatives is extremely important in the chemical industry. The use of photocatalysis in organic synthesis has attracted considerable attention among synthetic chemists because of its "green" environmental characteristics. In this study, nanoscale Bi2WO6 with a flower-like morphology was found to be a highly efficient photocatalyst in the catalytic oxidation of toluene and its derivatives using O-2 as the oxidant. The loading of Pd nanoparticles as a cocatalyst onto the flower-like Bi2WO6 was found to produce a significant enhancement in the catalytic activity. Mechanistic investigation showed that the superior performance of Pd/Bi2WO6 could be attributed to the improvement of both the reductive and oxidative abilities of Bi2WO6 by the loading of the cocatalyst. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000400125100005 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152013]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Bo,Zhang, Bao,Wang, Zhiliang,et al. Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(3):440-446. |
| APA | Yuan, Bo.,Zhang, Bao.,Wang, Zhiliang.,Lu, Shengmei.,Li, Jun.,...&Li, Can.(2017).Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6.CHINESE JOURNAL OF CATALYSIS,38(3),440-446. |
| MLA | Yuan, Bo,et al."Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6".CHINESE JOURNAL OF CATALYSIS 38.3(2017):440-446. |
入库方式： OAI收割
来源：大连化学物理研究所
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