High performance platinum single atom electrocatalyst for oxygen reduction reaction
文献类型：期刊论文
| 作者 | Liu, Jing1,2; Jiao, Menggai2,3; Lu, Lanlu4; Barkholtz, Heather M.5; Li, Yuping6; Wang, Ying7; Jiang, Luhua6; Wu, Zhijian3; Liu, Di-Jia5; Zhuang, Lin7 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2017-07-24 |
| 卷号 | 8 |
| DOI | 10.1038/ncomms15938 |
| 英文摘要 | For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/methanol tolerance for the cathodic oxygen reduction reaction. The acidic single-cell with such a catalyst as cathode delivers high performance, with power density up to 680 mW cm(-2) at 80 degrees C with a low platinum loading of 0.09 mg(Pt) cm(-2), corresponding to a platinum utilization of 0.13 g(Pt) kW(-1) in the fuel cell. Good fuel cell durability is also observed. Theoretical calculations reveal that the main effective sites on such platinum single-atom electrocatalysts are single-pyridinic-nitrogen-atom-anchored single-platinum-atom centres, which are tolerant to carbon monoxide/methanol, but highly active for the oxygen reduction reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000406144700001 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152029]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Jilin Prov Key Lab Low Carbon Chem Power, State Key Lab Electroanalyt Chem, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 5.Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA 6.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China 7.Wuhan Univ, Hubei Key Lab Electrochem Power Sources, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 8.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 9.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 10.Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany |
| 推荐引用方式 GB/T 7714 | Liu, Jing,Jiao, Menggai,Lu, Lanlu,et al. High performance platinum single atom electrocatalyst for oxygen reduction reaction[J]. NATURE COMMUNICATIONS,2017,8. |
| APA | Liu, Jing.,Jiao, Menggai.,Lu, Lanlu.,Barkholtz, Heather M..,Li, Yuping.,...&Sun, Gongquan.(2017).High performance platinum single atom electrocatalyst for oxygen reduction reaction.NATURE COMMUNICATIONS,8. |
| MLA | Liu, Jing,et al."High performance platinum single atom electrocatalyst for oxygen reduction reaction".NATURE COMMUNICATIONS 8(2017). |
入库方式： OAI收割
来源：大连化学物理研究所
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