Tandem catalytic synthesis of benzene from CO2 and H-2
文献类型：期刊论文
| 作者 | Zhu, Pengfei1,3; Sun, Jian2; Yang, Guohui3; Liu, Guoguo3; Zhang, Peipei3; Yoneyama, Yoshiharu3; Tsubaki, Noritatsu3 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2017-07-07 |
| 卷号 | 7页码:2695-2699 |
| DOI | 10.1039/c7cy00842b |
| 英文摘要 | Benzene as an important raw material for production of industrial chemicals is generally synthesized from petroleum and coal tar. Here, we realized the synthesis of benzene from greenhouse CO2 and H-2 with two connected reactors by a tandem catalysis reaction comprising CO2 methanation and CH4 aromatization. The Ni/SiO2 catalyst loaded in the first reactor was used to convert CO2 to CH4, and the formed CH4 was sequentially converted to benzene on the Mo/HZSM-5 catalyst in the second reactor. The benzene formation rate reaches 0.68 mu molg(-1) min(-1) accompanied by a high CO2 conversion of 92%. This concept will provide a new pathway for the direct synthesis of benzene and CO2 utilization. |
| 语种 | 英语 |
| WOS记录号 | WOS:000404887400004 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152056]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan |
| 推荐引用方式 GB/T 7714 | Zhu, Pengfei,Sun, Jian,Yang, Guohui,et al. Tandem catalytic synthesis of benzene from CO2 and H-2[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7:2695-2699. |
| APA | Zhu, Pengfei.,Sun, Jian.,Yang, Guohui.,Liu, Guoguo.,Zhang, Peipei.,...&Tsubaki, Noritatsu.(2017).Tandem catalytic synthesis of benzene from CO2 and H-2.CATALYSIS SCIENCE & TECHNOLOGY,7,2695-2699. |
| MLA | Zhu, Pengfei,et al."Tandem catalytic synthesis of benzene from CO2 and H-2".CATALYSIS SCIENCE & TECHNOLOGY 7(2017):2695-2699. |
入库方式： OAI收割
来源：大连化学物理研究所
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