A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters
文献类型：期刊论文
| 作者 | Zhou Yang1,2; Li Gao1 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2017-05-31 |
| 卷号 | 33页码:1297-1309 |
| 关键词 | Gold Cluster Carbon-carbon Coupling Ligand Engineering Doping Effect Ullmann Coupling Sonogashira Cross-coupling Suzuki Cross-coupling a(3)-coupling |
| DOI | 10.3866/PKU.WHXB201704101 |
| 英文摘要 | Well-defined gold nanoclusters have been documented as new and promising materials in the field of nanoscience. They have been well explored for the nanocatalysis of reactions like selective oxidation and hydrogenation, carbon-carbon coupling, etc. These Au nanoclusters possess unique electronic properties and crystal structure, which provide an excellent opportunity to correlate atomic structure with intrinsic catalytic property and to investigate the mechanisms of reactions over Au nanoclusters. In this review, we generalize the catalytic application of gold nanoclusters in carbon-carbon coupling reactions, including Ullmann, Sonogashira, Suzuki, and A(3)-coupling reactions. Herein, we have discussed ligand engineering (e.g., aromatic and aliphatic thiolate) as well as the effect of metal dopants (e.g., Cu, Ag, Pt, and Pd). Finally, the tentative catalytic mechanisms and the structure-performance relationships were discussed at the atomic level, which will give some clue for the design of efficient gold cluster catalysts. |
| 语种 | 英语 |
| WOS记录号 | WOS:000403249300008 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152102]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Yang,Li Gao. A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters[J]. ACTA PHYSICO-CHIMICA SINICA,2017,33:1297-1309. |
| APA | Zhou Yang,&Li Gao.(2017).A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters.ACTA PHYSICO-CHIMICA SINICA,33,1297-1309. |
| MLA | Zhou Yang,et al."A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters".ACTA PHYSICO-CHIMICA SINICA 33(2017):1297-1309. |
入库方式： OAI收割
来源：大连化学物理研究所
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