Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water
文献类型：期刊论文
| 作者 | Xu, Zhanwei; Yan, Peifang; Jiang, Hong; Liu, Kairui; Zhang, Z. Conrad |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 35页码:581-585 |
| 关键词 | Iridium Reductive Amination Hydrogenation Levulinic Acid Biomass |
| DOI | 10.1002/cjoc.201600726 |
| 英文摘要 | The synthesis of pyrrolidinones from reductive amination of levulinic acid (LA) with primary amines is reported. Pyrrolidinones have various applications such as surfactants, pharmaceutical intermediates, dispersants, and solvents. The half-sandwich Cp* Ir complex (Cp* is 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) coordinated by bipyridine ligand bearing both dimethylamino and ortho-hydroxyl groups showed high catalytic activity for the reductive amination of LA. A range of primary amines, such as aromatic and benzyl amines, were readily converted to corresponding pyrrolidinones in good yields. |
| 语种 | 英语 |
| WOS记录号 | WOS:000404028300009 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152109]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Zhanwei,Yan, Peifang,Jiang, Hong,et al. Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:581-585. |
| APA | Xu, Zhanwei,Yan, Peifang,Jiang, Hong,Liu, Kairui,&Zhang, Z. Conrad.(2017).Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water.CHINESE JOURNAL OF CHEMISTRY,35,581-585. |
| MLA | Xu, Zhanwei,et al."Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water".CHINESE JOURNAL OF CHEMISTRY 35(2017):581-585. |
入库方式： OAI收割
来源：大连化学物理研究所
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