State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates
文献类型：期刊论文
| 作者 | Wang, Wenlong2; Wang, Yuqing2,3; Li, Cunyao2; Yan, Li2; Jiang, Miao2; Ding, Yunjie1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 5页码:4523-4528 |
| 关键词 | Carbon Dioxide Polymeric Catalyst Heterogeneous Catalyst Cooperative Catalysis Cyclic Carbonates |
| DOI | 10.1021/acssuschemeng.7b00947 |
| 英文摘要 | A single-component multifunctional catalyst (denoted as Mg-por/pho@POP) based on a magnesium porphyrin and phosphonium salt-integrated porous organic polymer (POP) was afforded via a solvothermal synthetic technique for cyclic carbonate production which uses epoxides and CO2. In consequence of the cooperative (or synergistic) effect of a phosphonium salt and homogeneously dispersed magnesium porphyrin moiety, which is possibly reinforced through the flexible frameworks and confined microporous structure, this powerful catalyst offered the highest activity of a heterogeneous catalyst within the context of cyclic carbonates synthesis from epoxide and CO2 (turnover frequencies up to 15,600 h(-1)) without the addition of co-catalysts. More surprisingly, very promising turnover numbers (TONs) of 14,400 and 4200 were realized at very mild temperatures of 25 and 40 degrees C. Moreover, Mg-por/pho@POP can be simply recovered and reused at least five times. |
| 语种 | 英语 |
| WOS记录号 | WOS:000402950000007 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152184]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wenlong,Wang, Yuqing,Li, Cunyao,et al. State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5:4523-4528. |
| APA | Wang, Wenlong,Wang, Yuqing,Li, Cunyao,Yan, Li,Jiang, Miao,&Ding, Yunjie.(2017).State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5,4523-4528. |
| MLA | Wang, Wenlong,et al."State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5(2017):4523-4528. |
入库方式： OAI收割
来源：大连化学物理研究所
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