Attrition of methanol to olefins catalyst in jet cup
文献类型：期刊论文
| 作者 | Hao, Jingai1,2; Zhao, Yinfeng2; Ye, Mao2; Liu, Zhongmin2 |
| 刊名 | POWDER TECHNOLOGY
 |
| 出版日期 | 2017-07-01 |
| 卷号 | 316页码:79-86 |
| 关键词 | Attrition Mto Catalyst Jet Cup Gwyn Formulation |
| DOI | 10.1016/j.powtec.2016.12.091 |
| 英文摘要 | Attrition of catalyst in a fluidized bed reactor is an inevitable issue especially in a commercial unit. Methanol to olefins (MTO) is becoming one of the main stream technologies for light olefins production. The attrition of MTO catalyst, however, received little attention. This study is focused on the attrition behavior of MTO catalyst in jet cup at high temperature. The influence of test time, inlet gas velocity, and temperature on MTO catalyst attrition was studied. It is found that the Gwyn formulation can well represent the relation between attrition index and test time. Our results show that jet cup can retrieve results quantitatively comparable to high velocity gas jets method while significantly shortening test time. It is also found that the inlet gas velocity has considerable influence on the MTO catalyst attrition, and the relation between inlet gas velocities and attrition index can be described by a power index of 3.7. Similar to high velocity gas jets experiments the attrition index manifests a maximum with the increase of temperature. But the temperature corresponding to the maximum attrition index shifts from 300 degrees C in high velocity jets tests to 100 degrees C in jet cup experiments. An analysis based on SEM pictures indicates that the transition of attrition mechanism is responsible for this shift. An empirical correlation has been presented for MTO catalyst attrition in jet cup, which shows good agreement with experimental data for inlet gas velocity from 88 to 158 m/s, and temperature from 100 to 500 degrees C. (C) 2017 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000403510600009 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152187]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Natl Engn Lab MTO, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hao, Jingai,Zhao, Yinfeng,Ye, Mao,et al. Attrition of methanol to olefins catalyst in jet cup[J]. POWDER TECHNOLOGY,2017,316:79-86. |
| APA | Hao, Jingai,Zhao, Yinfeng,Ye, Mao,&Liu, Zhongmin.(2017).Attrition of methanol to olefins catalyst in jet cup.POWDER TECHNOLOGY,316,79-86. |
| MLA | Hao, Jingai,et al."Attrition of methanol to olefins catalyst in jet cup".POWDER TECHNOLOGY 316(2017):79-86. |
入库方式： OAI收割
来源：大连化学物理研究所
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