One-Pot Preparation of Macroporous Organic-Silica Monolith for the Organics-/Oil-Water Separation
文献类型：期刊论文
| 作者 | Liu, Zhongshan1,2; Ou, Junjie1; Wang, Hongwei1; Chen, Lianfang1,2; Xu, Junwen1,2; Ye, Mingliang1 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2017-05-31 |
| 卷号 | 2页码:4538-4544 |
| 关键词 | Click Polymerization Fast Swelling Hydrophobic Hybrid Monolith Oil-water Separation |
| DOI | 10.1002/slct.201700345 |
| 英文摘要 | Three-dimensional porous monoliths have been considered as attractive candidates for the organics-/oil-water separation due to their high porosity, low density and hydrophobic/oleophilic property. To simplify the preparation process, one-pot method based on thiol-methacrylate click polymerization was developed to fabricate macroporous organic-silica monolith by using octakis(3-mercaptopropyl)octasilsesquioxane, ethylene glycol dimethacrylate and heptadecafluorodecyl methacrylate as starting monomers. The rapid click polymerization was carried out at room temperature under air atmosphere, which made it possible for preparation of monolith with desired scale and geometry. The hybrid monolith with good thermal stability and compressibility generated through-pores with diameter ranging from several microns to tens of microns. As a result of the flexible organic linkages and fluorocarbon groups, the hybrid monolith showed hydrophobic feature, and could be fast swollen in organic liquids. Particularly, a cylindrical hybrid monolith (15 mm in diameter x 11 mm in height) supported by a modified syringe, which exhibited excellent recyclability and swelling-squeezing performance, has been applied to selectively absorb organic liquids located on the upper or under water layer. |
| 语种 | 英语 |
| WOS记录号 | WOS:000403256200035 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152198]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhongshan,Ou, Junjie,Wang, Hongwei,et al. One-Pot Preparation of Macroporous Organic-Silica Monolith for the Organics-/Oil-Water Separation[J]. CHEMISTRYSELECT,2017,2:4538-4544. |
| APA | Liu, Zhongshan,Ou, Junjie,Wang, Hongwei,Chen, Lianfang,Xu, Junwen,&Ye, Mingliang.(2017).One-Pot Preparation of Macroporous Organic-Silica Monolith for the Organics-/Oil-Water Separation.CHEMISTRYSELECT,2,4538-4544. |
| MLA | Liu, Zhongshan,et al."One-Pot Preparation of Macroporous Organic-Silica Monolith for the Organics-/Oil-Water Separation".CHEMISTRYSELECT 2(2017):4538-4544. |
入库方式： OAI收割
来源：大连化学物理研究所
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