Hybrid Polymer Nanoarrays with Bifunctional Conductance of Ions and Electrons and Enhanced Electrochemical Interfaces
文献类型：期刊论文
| 作者 | Xia, Zhangxun1; Sun, Ruili1,2; Wang, Suli1; Jiang, Luhua1; Sun, Hai1; Sun, Gongquan1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-05-31 |
| 卷号 | 9页码:18276-18282 |
| 关键词 | Conductive Polymer Electrochemistry Electrochemical Interfaces Ionic Conductance Nanomaterials |
| DOI | 10.1021/acsami.7b02649 |
| 英文摘要 | Ion migration and electron transfer are crucial phenomena in electrochemistry and interfacial sciences, which require effective coupling and integration of separated charge pathways within medium materials. Here, in this work, we fabricated an ordered nanowire material based on hybrid polymers of polypyrrole, with electronic conductance, and perfluorosulfonic acid ionomers, with ionic conductance, via a facile one-step electrochemical route. Because of the nanoconfined effects for the different charge-transfer channels within the nanowire polymer matrix, the electronic and ionic conductivities of the hybrid polymer are surprisingly enhanced, being 26.4 and 0.096 S cm(-1), respectively. Such an improvement in the formation of charge pathways also leads to an increased electrochemical capacitance through enlargement of the area of ion/electron transport boundaries, which may show great potential in the applications of supercapacitors, fuel cells, rechargeable batteries, and other electrochemical devices. |
| 语种 | 英语 |
| WOS记录号 | WOS:000402691600070 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152218]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Div Fuel Cells & Battery, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Zhangxun,Sun, Ruili,Wang, Suli,et al. Hybrid Polymer Nanoarrays with Bifunctional Conductance of Ions and Electrons and Enhanced Electrochemical Interfaces[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9:18276-18282. |
| APA | Xia, Zhangxun,Sun, Ruili,Wang, Suli,Jiang, Luhua,Sun, Hai,&Sun, Gongquan.(2017).Hybrid Polymer Nanoarrays with Bifunctional Conductance of Ions and Electrons and Enhanced Electrochemical Interfaces.ACS APPLIED MATERIALS & INTERFACES,9,18276-18282. |
| MLA | Xia, Zhangxun,et al."Hybrid Polymer Nanoarrays with Bifunctional Conductance of Ions and Electrons and Enhanced Electrochemical Interfaces".ACS APPLIED MATERIALS & INTERFACES 9(2017):18276-18282. |
入库方式： OAI收割
来源：大连化学物理研究所
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