Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide
文献类型：期刊论文
| 作者 | Zhang, Jian1,2; Ni, Xiao-Lei1; Liu, Jing1; Liu, Ying-Ya1; Leus, Karen4; Depauw, Hannes4; Wang, An-Jie1,3; Van Der Voort, Pascal4; Hu, Yong-Kang1,3 |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 28页码:1057-1061 |
| 关键词 | Metal-organic Framework Molybdenum Cumene Hydroperoxide Propylene Epoxidation |
| DOI | 10.1016/j.cclet.2017.01.020 |
| 英文摘要 | Two types of Mo containing metal-organic frameworks, denoted as Mo@COMOC-4 and PMA@MIL-101 (Cr), were synthesized respectively by a post-synthetic modification and a ship-in-bottle approach. The catalytic performance of both compounds in the epoxidation of propylene using cumene hydroperoxide (CHP) as oxidant was compared with MoO3@SiO2. A higher conversion (46.2%) and efficiency (87.4%) of CHP was observed for Mo@COMOC-4, whereas the heteropoly acids supported MIL-101 resulted in the decomposition of CHP due to its strong acidic character. Regenerability tests demonstrated that Mo@COMOC-4 could be reused for multiple runs without significant loss in both activity and stability. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000402444600026 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152223]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Liaoning Key Lab Petrochem Technol & Equipments, Dalian 116024, Peoples R China 4.Univ Ghent, Dept Inorgan & Phys Chem, COMOC, Krijgslaan 281-S3, B-9000 Ghent, Belgium |
| 推荐引用方式 GB/T 7714 | Zhang, Jian,Ni, Xiao-Lei,Liu, Jing,et al. Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide[J]. CHINESE CHEMICAL LETTERS,2017,28:1057-1061. |
| APA | Zhang, Jian.,Ni, Xiao-Lei.,Liu, Jing.,Liu, Ying-Ya.,Leus, Karen.,...&Hu, Yong-Kang.(2017).Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide.CHINESE CHEMICAL LETTERS,28,1057-1061. |
| MLA | Zhang, Jian,et al."Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide".CHINESE CHEMICAL LETTERS 28(2017):1057-1061. |
入库方式： OAI收割
来源：大连化学物理研究所
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