Enantioselective synthesis of quaternary alpha-aminophosphonates by organocatalytic Friedel-Crafts reactions of indoles with cyclic alpha-ketiminophosphonates
文献类型：期刊论文
| 作者 | Yan, Zhong; Gao, Xiang; Zhou, Yong-Gui |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 38页码:784-792 |
| 关键词 | Friedel-crafts Reaction Quaternary Alpha-aminophosphonate Indole Chiral Phosphoric Acid |
| DOI | 10.1016/S1872-2067(17)62804-3 |
| 英文摘要 | An efficient asymmetric Friedel-Crafts reaction has been developed for the synthesis of optically active quaternary alpha-aminophosphonates with up to 98% ee. The synthesis involves the reaction of cyclic alpha-ketiminophosphonates with indoles using an H8-BINOL-derived chiral phosphoric acid (CPA) catalyst that bears electron-withdrawing 3,5-ditrifluoromethylphenyl substituents on its 3- and 3'-positions. This Friedel-Crafts reaction of cyclic alpha-ketiminophosphonates was also successful with pyrrole. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000402346400003 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152281]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Zhong,Gao, Xiang,Zhou, Yong-Gui. Enantioselective synthesis of quaternary alpha-aminophosphonates by organocatalytic Friedel-Crafts reactions of indoles with cyclic alpha-ketiminophosphonates[J]. CHINESE JOURNAL OF CATALYSIS,2017,38:784-792. |
| APA | Yan, Zhong,Gao, Xiang,&Zhou, Yong-Gui.(2017).Enantioselective synthesis of quaternary alpha-aminophosphonates by organocatalytic Friedel-Crafts reactions of indoles with cyclic alpha-ketiminophosphonates.CHINESE JOURNAL OF CATALYSIS,38,784-792. |
| MLA | Yan, Zhong,et al."Enantioselective synthesis of quaternary alpha-aminophosphonates by organocatalytic Friedel-Crafts reactions of indoles with cyclic alpha-ketiminophosphonates".CHINESE JOURNAL OF CATALYSIS 38(2017):784-792. |
入库方式： OAI收割
来源：大连化学物理研究所
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