Au38S2(SAdm)(20) Photocatalyst for One-Step Selective Aerobic Oxidations
文献类型：期刊论文
| 作者 | Li, Zhimin2; Liu, Chao2; Abroshan, Hadi1; Kauffman, Douglas R.3; Li, Gao2 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 7页码:3368-3374 |
| 关键词 | Au Nanocluster Au-38 Singlet Oxygen Aerobic Oxidation Photocatalysis Sulfoxidation |
| DOI | 10.1021/acscatal.7b00239 |
| 英文摘要 | We here report a protocol for the synthesis of Au38S2(SAdm)(20) nanoclusters (-SAdm = 1-adamantanethiolate) with a higher production yield (10%) in comparison to previous reported methods. The photosensitizing properties of the gold nanoclusters are investigated for the formations of singlet oxygen (O-1(2)) using visible light wavelengths of 532 and 650 nm. The formation of O-1(2) was detected by 1,3-diphenylisobenzofuran as the chemical trapping probe as well as direct observation of the characteristic O-1(2) emission (ca. 1276 nm). The efficiency of the O-1(2) formation using the Au38S2(SAdm)(20) nanoclusters is found to be notably higher than that of Au-25(SR)(18) nanoclusters. Finally, selective aerobic oxidations of sulfide to sulfoxide and benzylamine to imine in the presence of oxygen (O-3(2)) and photoexcited Au38S2(SAdm)(20) are well studied. This work demonstrates the promise of Au38S2(SAdm)(20) nanoclusters in the generation of activated singlet oxygen for selective catalytic reactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000401054300034 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/152306]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China 3.US DOE, NETL, Pittsburgh, PA 15236 USA |
| 推荐引用方式 GB/T 7714 | Li, Zhimin,Liu, Chao,Abroshan, Hadi,et al. Au38S2(SAdm)(20) Photocatalyst for One-Step Selective Aerobic Oxidations[J]. ACS CATALYSIS,2017,7:3368-3374. |
| APA | Li, Zhimin,Liu, Chao,Abroshan, Hadi,Kauffman, Douglas R.,&Li, Gao.(2017).Au38S2(SAdm)(20) Photocatalyst for One-Step Selective Aerobic Oxidations.ACS CATALYSIS,7,3368-3374. |
| MLA | Li, Zhimin,et al."Au38S2(SAdm)(20) Photocatalyst for One-Step Selective Aerobic Oxidations".ACS CATALYSIS 7(2017):3368-3374. |
入库方式： OAI收割
来源：大连化学物理研究所
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