Bifunctional Ligand Enables Efficient Gold-Catalyzed Hydroalkenylation of Propargylic Alcohol
文献类型：期刊论文
| 作者 | Cheng, XP; Liao, SR; Porta, A; Ma, X; Zanoni, G; Zhang, LM |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:27页码:8250-8254 |
| 通讯作者 | gz@unipv.it ; zhang@chem.ucsb.edu |
| 英文摘要 | Using the previously designed biphenyl-2-ylphosphine ligand, featuring a remote tertiary amino group, the first gold-catalyzed intermolecular hydroalkenylation of alkynes has been developed. Synthetically valuable conjugated dienyl alcohols are formed in moderate to good yields. A range of alkenyltrifluoroborates are allowed as the alkenyl donor, and no erosion of alkene geometry and/or the propargylic configuration are detected. DFT calculations confirm the critical role of the remote basic group in the ligand as a general-base catalyst for promoting this novel gold catalysis with good efficiency. |
| 学科主题 | Chemistry |
| 关键词[WOS] | conjugation ; gold ; ligand design ; reaction mechanisms ; synthetic methods |
| 源URL | [http://ir.scsio.ac.cn/handle/344004/16923]  |
| 专题 | 南海海洋研究所_中科院海洋生物资源可持续利用重点实验室 |
| 推荐引用方式 GB/T 7714 | Cheng, XP,Liao, SR,Porta, A,et al. Bifunctional Ligand Enables Efficient Gold-Catalyzed Hydroalkenylation of Propargylic Alcohol[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(27):8250-8254. |
| APA | Cheng, XP,Liao, SR,Porta, A,Ma, X,Zanoni, G,&Zhang, LM.(2018).Bifunctional Ligand Enables Efficient Gold-Catalyzed Hydroalkenylation of Propargylic Alcohol.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(27),8250-8254. |
| MLA | Cheng, XP,et al."Bifunctional Ligand Enables Efficient Gold-Catalyzed Hydroalkenylation of Propargylic Alcohol".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.27(2018):8250-8254. |
入库方式： OAI收割
来源：南海海洋研究所
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