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Synthesis, characterization, and antifungal property of starch derivatives modified with quaternary phosphonium salts

文献类型：期刊论文

作者Tan, Wenqiang1,2; Li, Qing1; Wei, Lijie1,2; Wang, Ping3; Gao, Zhenpeng4; Chen, Yuan5; Dong, Fang1; Guo, Zhanyong1,2; Wang, Ping(Binzhou Med Univ Hosp, Dept Infect Dis, Binzhou 256603, Peoples R China); Guo, Zhanyong(Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China)
刊名MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
出版日期2017-07-01
卷号76页码:1048-1056
关键词Starch Derivatives Antifungal Activity Quaternary Phosphonium Salts Chain Length Electron-withdrawing Ability Biomaterials
ISSN号0928-4931
DOI10.1016/j.msec.2017.03.181
产权排序第1完成单位
文献子类Article
英文摘要Four novel starch derivatives modified with quaternary phosphonium salts were designed and successfully synthesized, including trimethylphosphonium acetyl starch chloride, tributylphosphonium acetyl starch chloride, tricyclohexylphosphonium acetyl starch chloride, triphenylphosphonium acetyl starch chloride, and characterized by FTIR, UV, H-1 NMR, C-13 NMR, and P-31 NMR spectra. Their antifungal activities against four kinds of phytopathogens were evaluated using the radial growth assay and minimum inhibitory concentration procedure. The fungicidal assessment revealed that the synthesized starch derivatives had superior antifungal activity compared with starch. Especially, the inhibitory indices of triphenylphosphonium acetyl starch chloride against these four kinds of plant pathogens were higher than 70% at 1.0 mg/mL. The results indicated that quaternary phosphonium groups should be high-efficiency antifungal function groups, and meanwhile longer alkyl chain lengths or the stronger electron-withdrawing groups were responsible for enhanced antifungal versatility and efficacy. The cytotoxicity of starch and starch derivatives bearing quaternary phosphonium salts was evaluated in vitro on HEK-293T cells. As novel quaternary phosphoniuni functionalized starch derivatives could be prepared efficiently and exhibited superduper antifungal activity, this synthetic strategy might provide an effective way and notion to prepare novel antifungal biomaterials. (C) 2017 Published by Elsevier B.V.
URL标识查看原文
WOS关键词FUNCTIONALIZED CHITOSAN DERIVATIVES ; DIFFERENT AMYLOSE CONTENTS ; ANTIBACTERIAL ACTIVITY ; PHYSICOCHEMICAL PROPERTIES ; ANTIMICROBIAL ACTIVITY ; INULIN DERIVATIVES ; CROSS-LINKING ; AMMONIUM ; COPOLYMERS ; ALCOHOL
WOS研究方向Materials Science
语种英语
WOS记录号WOS:000405541600120
资助机构National Natural Science Foundation of China(41576156) ; Shandong Province Science and Technology Development Plan(2015GSF121045) ; Yantai Science and Technology Development Plan(2015ZH078) ; Public Science and Technology Research Funds Projects of Ocean(201505022-3)
源URL[http://ir.yic.ac.cn/handle/133337/22569]  
专题海岸带生物资源高效利用研究与发展中心
烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室
烟台海岸带研究所_污染过程与控制实验室
通讯作者Wang, Ping; Guo, Zhanyong; Wang, Ping(Binzhou Med Univ Hosp, Dept Infect Dis, Binzhou 256603, Peoples R China); Guo, Zhanyong(Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China)
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Binzhou Med Univ Hosp, Dept Infect Dis, Binzhou 256603, Peoples R China
4.Harbin Inst Technol Weihai, Sch Marine Sci & Technol, Weihai 264209, Peoples R China
5.Yantai Univ, Sch Ocean, Yantai 264005, Peoples R China
推荐引用方式
GB/T 7714		 Tan, Wenqiang,Li, Qing,Wei, Lijie,et al. Synthesis, characterization, and antifungal property of starch derivatives modified with quaternary phosphonium salts[J]. MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS,2017,76:1048-1056.
APA Tan, Wenqiang.,Li, Qing.,Wei, Lijie.,Wang, Ping.,Gao, Zhenpeng.,...&Guo, Zhanyong.(2017).Synthesis, characterization, and antifungal property of starch derivatives modified with quaternary phosphonium salts.MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS,76,1048-1056.
MLA Tan, Wenqiang,et al."Synthesis, characterization, and antifungal property of starch derivatives modified with quaternary phosphonium salts".MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS 76(2017):1048-1056.

入库方式： OAI收割

来源：烟台海岸带研究所

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