Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles
文献类型：期刊论文
| 作者 | Kantekin Halit ; Bakaray Asiye ; Ocak Miraç ; Alp Hakan ; Ocak Ümmühan |
| 刊名 | Separation Science and Technology
 |
| 出版日期 | 2007 |
| 卷号 | 42期号:14页码:3243-3257 |
| 关键词 | Extraction Constant Solvent Extraction Mixed-donor Macrocycle Macrocyclic Complex TransitIon Metal Ion |
| ISSN号 | 0149-6395 |
| 英文摘要 | Synthetic procedures for new mixed-donor macrocycle compounds were reported. The macrocyclic compounds were used in solvent extraction metal picrates such as Ag+, Hg2+, Cd2+, Zn2+, Cu2+, Ni2+, Mn2+, Pb2+, and Co2+. The metal picrate extractions were investigated at 25±0.1°C with the aid of UV-visible spectrometry. It was found that 6,7,9,10,12,13,23,24-octahydro-19H,26Hdibenzo[h,t](1,4,7,13,16,22,10,19) dioxatetrathiadiazasiclotetracosine-20,27(21H,28H)-dione showed selectivity towards Ag+, Hg2+, and Cd2+ among the other metals. The extraction constants (Log Kex) and complex compositions were determined for the Ag+ and Hg2+ complexes for this compound and 9,10,12,13,23,24,26,27,29,30-decahydro-5H,15H-dibenzo-[h,w][1,4,7,13,16,19,25-,10,22] dioxapentathiadiazacycloheptacosine-6,16(7H,17H)-dione. |
| 公开日期 | 2011-01-07 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/3162]  |
| 专题 | 烟台海岸带研究所_科研共享资源 |
| 推荐引用方式 GB/T 7714 | Kantekin Halit,Bakaray Asiye,Ocak Miraç,et al. Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles[J]. Separation Science and Technology,2007,42(14):3243-3257. |
| APA | Kantekin Halit,Bakaray Asiye,Ocak Miraç,Alp Hakan,&Ocak Ümmühan.(2007).Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles.Separation Science and Technology,42(14),3243-3257. |
| MLA | Kantekin Halit,et al."Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles".Separation Science and Technology 42.14(2007):3243-3257. |
入库方式： OAI收割
来源：烟台海岸带研究所
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