Catalytic hydrodechlorination reactivity of monochlorophenols in aqueous solutions over palladium/carbon catalyst
文献类型：期刊论文
| 作者 | Xia, Chuanhai1,2 ; Liu, Ying1; Xu, Jie2; Yu, Junbao1; Qin, Wei1; Liang, Xinmiao2
|
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2009-01-25 |
| 卷号 | 10期号:5页码:456-458 |
| 关键词 | Catalytic Hydrodechlorination Palladium/carbon Monochlorophenols Hydrodechlorination Reactivity Aqueous Solutions |
| 产权排序 | CAS, Yantai Inst Coastal Zone Res Sustainable Dev;CAS, Dalian Inst Chem Phys |
| 通讯作者 | Xia, CH, CAS, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China |
| 文献子类 | Article |
| 英文摘要 | Monochlorophenols (CPs) were completely hydrodechlorinated with 5% Pd/C in aqueous solutions at room temperature under atmospheric pressure. In the hydrogenation process, 2-CP, 3-CP and 4-CP showed different clechlorination reactivity. It was found the C-Cl bond in the ortho position of hydroxyl group was the most difficult clechlorination in the hydrogenation of monochlorophenols in aqueous solutions compared to those in meta and para positions. Additionally. bases and solvents also had influences on the hydrodechlorination reactivity and selectivity of monochlorophenols as well as the activity of the catalyst. In aqueous solutions, it was more advantageous to the hydrodechlorination of monochlorophenols during the hydrogenation due to the cleaning function of water. Furthermore, the presence of bases, especially for sodium hydroxide, also ensured the high activity of the catalyst in water. (C) 2008 Elsevier B.V. All rights reserved. |
| 学科主题 | Chemistry ; Physical |
| WOS关键词 | LIQUID-PHASE HYDRODECHLORINATION ; RANEY-NICKEL CATALYST ; MILD CONDITIONS ; SUPPORTED CATALYSTS ; HYDROGEN GAS ; FLY-ASH ; WATER ; HYDRODEHALOGENATION ; DECHLORINATION ; CHLOROPHENOLS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000263864900009 |
| 资助机构 | Yantai Science & Technology Bureau [2008155]; Department of Science & Technology of Shandong Province [2006GG2205033] |
| 源URL | [http://ir.yic.ac.cn/handle/133337/3472]  |
| 专题 | 烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室 烟台海岸带研究所_滨海湿地实验室 |
| 作者单位 | 1.CAS, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China 2.CAS, Dalian Inst Chem Phys, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Chuanhai,Liu, Ying,Xu, Jie,et al. Catalytic hydrodechlorination reactivity of monochlorophenols in aqueous solutions over palladium/carbon catalyst[J]. CATALYSIS COMMUNICATIONS,2009,10(5):456-458. |
| APA | Xia, Chuanhai,Liu, Ying,Xu, Jie,Yu, Junbao,Qin, Wei,&Liang, Xinmiao.(2009).Catalytic hydrodechlorination reactivity of monochlorophenols in aqueous solutions over palladium/carbon catalyst.CATALYSIS COMMUNICATIONS,10(5),456-458. |
| MLA | Xia, Chuanhai,et al."Catalytic hydrodechlorination reactivity of monochlorophenols in aqueous solutions over palladium/carbon catalyst".CATALYSIS COMMUNICATIONS 10.5(2009):456-458. |
入库方式： OAI收割
来源：烟台海岸带研究所
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