The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst
文献类型：期刊论文
| 作者 | Ma, Xuanxuan1,2; Zhou, Shiwei1; Yang, Cuiyun1 ; Liu, Sujing1; Bi, Xiaoli1; Xia, Chuanhai1
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| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2010-12-15 |
| 卷号 | 12期号:4页码:282-285 |
| 关键词 | Hydrodechlorination (Hdcl) Triethylamine (Et3n) Raney Ni Chlorophenol (Cp) Catalytic Reactivity/selectivity |
| 产权排序 | (1) Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences;(2) Graduate School, Chinese Academy of Sciences; |
| 通讯作者 | Xia, C. (chxia@yic.ac.cn) |
| 文献子类 | Article |
| 英文摘要 | The hydrodechlorination (HDCl) of 2,4-dichlorophenol (2,4-DCP), 2-chlorophenol (2-CP) and 4-chlorophenol (4-CP) over Raney Ni in liquid phase with triethylamine (Et3N) under mild conditions was studied. The results showed that Et3N together with solvents significantly affected the HDCl reactivity or selectivity, in which ortho-positioned Cl of chlorophenols (CPs) was easier to be dechlorinated in methanol (MeOH) and ethanol (EtOH), whereas para-positioned Cl was preferentially dechlorinated in water. Different species and action mechanisms of Et3N in water and organic solvents possibly affected the HDCl reactivity or selectivity of CPs over Raney Ni.; The hydrodechlorination (HDCl) of 2 4-dichlorophenol (2 4-DCP) 2-chlorophenol (2-CP) and 4-chlorophenol (4-CP) over Raney Ni in liquid phase with triethylamine (Et3N) under mild conditions was studied The results showed that Et3N together with solvents significantly affected the HDCl reactivity or selectivity in which ortho-positioned Cl of chlorophenols (CPs) was easier to be dechlorinated in methanol (MeOH) and ethanol (EtOH) whereas para-positioned Cl was preferentially dechlorinated in water Different species and action mechanisms of Et3N in water and organic solvents possibly affected the HDCl reactivity or selectivity of CPs over Raney Ni (C) 2010 Elsevier BV All rights reserved |
| WOS关键词 | LIQUID-PHASE HYDRODECHLORINATION ; MILD CONDITIONS ; AQUEOUS-SOLUTIONS ; PD/C ; 2,4-DICHLOROPHENOL ; PD/AL2O3 ; HYDROGENATION ; TEMPERATURE ; HYDROGENOLYSIS ; DEACTIVATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000285438300009 |
| 公开日期 | 2011-07-14 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/3672]  |
| 专题 | 烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Xuanxuan,Zhou, Shiwei,Yang, Cuiyun,et al. The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst[J]. CATALYSIS COMMUNICATIONS,2010,12(4):282-285. |
| APA | Ma, Xuanxuan,Zhou, Shiwei,Yang, Cuiyun,Liu, Sujing,Bi, Xiaoli,&Xia, Chuanhai.(2010).The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst.CATALYSIS COMMUNICATIONS,12(4),282-285. |
| MLA | Ma, Xuanxuan,et al."The influence of triethylamine on the hydrodechlorination reactivity of chlorophenols over Raney Ni catalyst".CATALYSIS COMMUNICATIONS 12.4(2010):282-285. |
入库方式： OAI收割
来源：烟台海岸带研究所
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