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A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes

文献类型：期刊论文

作者Lin, Mingyue1,3,4; Li, Jiezhen1; Pan, Dawei3; Bond, Alan M.1,2; Zhang, Jie1,2; Bond, Alan M.(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia); Zhang, Jie(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia)
刊名ELECTROCHIMICA ACTA
出版日期2017-09-01
卷号249页码:421-430
关键词Fe-iii/ii Process Electron Transfer Kinetics Fourier Transformed Alternating Current Voltammetry Medium Effect Electrode Heterogeneity
ISSN号0013-4686
DOI10.1016/j.electacta.2017.07.155
产权排序第3完成单位
文献子类Article
英文摘要The heterogeneous electron transfer kinetics (k(0) values), mass transport and thermodynamic properties (E-0 values) associated with the Fe-III/II process have been determined in aqueous solutions containing 0.1 M HCl, HClO4, bis(trifluoromethanesulfonyl) imide (HNTf2) or 0.05 M silicotungstic acid (H-4[alpha-SiW12O40]) supporting electrolytes. The diffusion coefficient (D) values for Fe-III and Fe-II are dependent on the radius of the electrolyte anion and follow the order D(SiW12O404-) < D(NTf2-) < D (ClO4-) < D(Cl-). The k(0) values are found to be smaller at boron doped diamond (BDD) electrodes than glassy carbon (GC) electrodes, and influenced by the ion-pairing between electrolyte anions and FeIII and FeII. Based on the formal potential value, HNTf2 is found to be a more innocent electrolyte than commonly used HClO4 with regard to determine the true k(0) values of the outer-sphere [Fe(H2O)(6)](3+/2+) process. Fourier transformed large amplitude alternating current voltammetry, which provides favorable signal to background ratio, was used to determine k(0) values associated with the Fe-III/II process in H-4[alpha-SiW12O40] and HNTf2 electrolyte media at GC electrodes and probe the implications of the heterogeneity of the BDD electrode surface on the electrode kinetic determination in H-4[alpha-SiW12O40] electrolyte media. (C) 2017 Elsevier Ltd. All rights reserved.
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WOS关键词THIN-FILM ELECTRODES ; ALTERNATING-CURRENT VOLTAMMETRY ; CYCLIC VOLTAMMETRY ; IONIC LIQUIDS ; ELECTROCHEMICAL-BEHAVIOR ; DISK ELECTRODE ; REDOX COUPLE ; SURFACE ; REDUCTION ; CHEMISTRY
WOS研究方向Electrochemistry
语种英语
WOS记录号WOS:000410675100048
资助机构University of Chinese Academy of Sciences ; Monash University ; Australian Research Council
源URL[http://ir.yic.ac.cn/handle/133337/23435]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者Bond, Alan M.; Zhang, Jie; Bond, Alan M.(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia); Zhang, Jie(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia)
作者单位1.Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
2.Monash Univ, ARC Ctr Excellence Electrochem Sci, Clayton, Vic 3800, Australia
3.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Shandong Prov Key Lab Coastal Environm Proc,YICCA, Yantai 264003, Shandong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Lin, Mingyue,Li, Jiezhen,Pan, Dawei,et al. A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes[J]. ELECTROCHIMICA ACTA,2017,249:421-430.
APA Lin, Mingyue.,Li, Jiezhen.,Pan, Dawei.,Bond, Alan M..,Zhang, Jie.,...&Zhang, Jie.(2017).A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes.ELECTROCHIMICA ACTA,249,421-430.
MLA Lin, Mingyue,et al."A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes".ELECTROCHIMICA ACTA 249(2017):421-430.

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来源：烟台海岸带研究所

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