中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation

文献类型:期刊论文

作者An, Xiaochan1,3; Liu, Zhongyun1; Hu, Yunxia2
刊名DESALINATION
出版日期2018-04-15
卷号432页码:23-31
关键词Amphiphobic Surface Modification Membrane Distillation Anti-wetting Electrospinning Nanofibrous Membrane
ISSN号0011-9164
DOI10.1016/j.desal.2017.12.063
文献子类Article
英文摘要Membrane distillation (MD) works as a promising alternative of RO to desalinate hypersaline water owing to its unique advantages including high concentration brine tolerance, 100% theoretical solute rejection, and low operating pressure. Hydrophobic MD membranes face critical challenge to treat industrial wastewaters containing low surface tension substances because these substances led to membrane wetting with loss of membrane permeability and rejection. In this study, we report a simple and facile approach to fabricate amphiphobic polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) electrospun nanofibrous membranes with anti wetting property. 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FAS) was used to fluorinate PVDF-HFP fibers and was then crosslinked to form a network upon dealcoholization under thermal treatment. The FAS-coated PVDF-HFP nanofibrous membranes exhibited great stable amphiphobicity with high contact angles against both water and oil, even challenged under critical conditions including boiling water, and strong base and acid etchings. Surface fluorination of PVDF-HFP nanofibrous membrane with the FAS coating did not sacrifice its permeate flux and salt rejection much. The fabricated amphiphobic nanofibrous membrane exhibited robust MD performance in the long-term operation and also in the presence of surfactant sodium dodecyl sulfate in the feed saline solution.
WOS关键词SUPEROLEOPHOBIC SURFACES ; SUPERAMPHIPHOBIC FABRICS ; WASTE-WATER ; ROBUST ; COATINGS ; DESALINATION ; POLYMER ; ENVIRONMENT ; TECHNOLOGY ; SEPARATION
WOS研究方向Engineering ; Water Resources
语种英语
WOS记录号WOS:000428103300003
出版者ELSEVIER SCIENCE BV
资助机构National Natural Science Foundation of China(21476249) ; Key Science and Technology Program of Yantai City(2015ZH063) ; State Key Laboratory of Separation Membranes and Membrane Processes (Tianjin Polytechnic University)(M1-201503)
源URL[http://ir.yic.ac.cn/handle/133337/24026]  
专题烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者Hu, Yunxia
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol Shandong, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
2.Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
An, Xiaochan,Liu, Zhongyun,Hu, Yunxia. Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation[J]. DESALINATION,2018,432:23-31.
APA An, Xiaochan,Liu, Zhongyun,&Hu, Yunxia.(2018).Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation.DESALINATION,432,23-31.
MLA An, Xiaochan,et al."Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation".DESALINATION 432(2018):23-31.

入库方式: OAI收割

来源:烟台海岸带研究所

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