Potentiometric sensor based on molecularly imprinted polymer for determination of melamine in milk
文献类型：期刊论文
| 作者 | Liang, Rongning1,2,3 ; Zhang, Ruiming1,3; Qin, Wei1,4
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| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
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| 出版日期 | 2009-09-07 |
| 卷号 | 141期号:2页码:544-550 |
| 关键词 | Molecularly Imprinted Polymer Potentiometric Sensor Melamine Ion-selective Electrode Flow Analysis |
| 产权排序 | Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev;Chinese Acad Sci, S China Sea Inst Oceanol;Chinese Acad Sci, Grad Sch;Yantai Univ, Sch Oceanol |
| 通讯作者 | Qin, W, Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China |
| 文献子类 | Article |
| 英文摘要 | A polymeric membrane ion-selective electrode for determination of melamine is described in this paper. it is based on a molecularly imprinted polymer (MIP) for selective recognition, which can be synthesized by using melamine as a template molecule, methacrylic acid as a functional monomer and ethylene glycol dimethacrylate as a cross-linking agent. The membrane electrode shows near-Nernstian response (54 mV/decade) to the protonated melamine over the concentration range of 5.0 x 10(-6) to 1.0 x 10(-2) mol L(-1). The electrode exhibits a short response time of similar to 16 s and can be stable for more than 2 months. Combined with flow analysis system, the potentiometric sensor has been successfully applied to the determination of melamine in milk samples. Interference from high concentrations of ions co-existing in milk samples such as K(+) and Na(+) can be effectively eliminated by on-line introduction of anion- and cation-exchanger tandem columns placed upstream, while melamine existing as neutral molecules in milk of pH 6.7 can flow through the ion-exchanger columns and be measured downstream by the proposed electrode in an acetate buffer solution of pH 3.7. (C) 2009 Elsevier BY. All rights reserved. |
| 学科主题 | Chemistry ; Analytical ; Electrochemistry ; Instruments & Instrumentation |
| WOS关键词 | ION-SELECTIVE ELECTRODES ; SOLID-PHASE EXTRACTION ; LIQUID-CHROMATOGRAPHY ; BIOMIMETIC SENSORS ; RECOGNITION ; MEMBRANES ; ATRAZINE ; PROTAMINE ; RESIDUES ; BINDING |
| WOS研究方向 | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
| 语种 | 英语 |
| WOS记录号 | WOS:000270343000030 |
| 资助机构 | Chinese Academy of Sciences [KZCX2-YW-410]; National Natural Science Foundation of China [40776058]; Ministry of Science and Technology of China [2007AA09Z103]; Department of Science and Technology of Shandong Province [2006GG2205033]; Outstanding Youth N |
| 源URL | [http://ir.yic.ac.cn/handle/133337/3444]  |
| 专题 | 烟台海岸带研究所_近岸生态与环境实验室 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China 2.Chinese Acad Sci, S China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Yantai Univ, Sch Oceanol, Yantai 264005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Rongning,Zhang, Ruiming,Qin, Wei. Potentiometric sensor based on molecularly imprinted polymer for determination of melamine in milk[J]. SENSORS AND ACTUATORS B-CHEMICAL,2009,141(2):544-550. |
| APA | Liang, Rongning,Zhang, Ruiming,&Qin, Wei.(2009).Potentiometric sensor based on molecularly imprinted polymer for determination of melamine in milk.SENSORS AND ACTUATORS B-CHEMICAL,141(2),544-550. |
| MLA | Liang, Rongning,et al."Potentiometric sensor based on molecularly imprinted polymer for determination of melamine in milk".SENSORS AND ACTUATORS B-CHEMICAL 141.2(2009):544-550. |
入库方式： OAI收割
来源：烟台海岸带研究所
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