中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sequential extraction procedures for the determination of phosphorus forms in sediment

文献类型:期刊论文

作者Wang, Changyou1; Zhang, Yong2; Li, Hongli1; Morrison, R. John3
刊名LIMNOLOGY
出版日期2013-04-01
卷号14期号:2页码:147-157
ISSN号1439-8621
关键词Phosphorus Extraction Sediment Forms
通讯作者Wang, CY (reprint author), Nanjing Univ Informat Sci & Technol, Sch Marine Sci, Nanjing 210044, Jiangsu, Peoples R China. chy.w@hotmail.com
产权排序[Wang, Changyou; Li, Hongli] Nanjing Univ Informat Sci & Technol, Sch Marine Sci, Nanjing 210044, Jiangsu, Peoples R China; [Zhang, Yong] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China; [Morrison, R. John] Univ Wollongong, Sch Earth & Environm Sci, Wollongong, NSW 2522, Australia
文献子类Review
英文摘要This article summarizes the main extraction methods for sedimentary phosphorus (P) determination. With sequential chemical extractions, P is supposed to be selectively removed from different compounds in the sediments. Extraction schemes using strong acids and alkaline solutions have been tested on different sediments and found not to extract well-defined fractions. In addition, several systematic errors in these schemes have been detected. Thus, these schemes have been modified and simplified accordingly. The Standards Measurements and Testing Program of the European Commission (SMT) method is a popular modification of these extraction schemes, as it is simple to handle, allows laboratories to achieve reproducible results and could provide a useful tool for routine use by water managers. The SEDEX (sequential extraction method) method, another popular modification, is widely applied in biogeochemical research as it can separate authigenic carbonate fluorapatite from fluorapatite. Other chemical extractions using chelating compounds have attempted to extract P bound with iron and calcium in sediments without disturbing clay-bound or organic P, the purpose being to determine the algal-available non-apatite, apatite and organic fractions of sediment P. All extraction procedures still yield operationally defined fractions and cannot be used for identification of discrete P compounds. Future modifications of the extraction scheme should aim to achieve better extraction efficiency and selectivity, simple handling techniques and methods that can prevent the extracted P from being re-adsorbed onto Fe(OOH) and CaCO3.; This article summarizes the main extraction methods for sedimentary phosphorus (P) determination. With sequential chemical extractions, P is supposed to be selectively removed from different compounds in the sediments. Extraction schemes using strong acids and alkaline solutions have been tested on different sediments and found not to extract well-defined fractions. In addition, several systematic errors in these schemes have been detected. Thus, these schemes have been modified and simplified accordingly. The Standards Measurements and Testing Program of the European Commission (SMT) method is a popular modification of these extraction schemes, as it is simple to handle, allows laboratories to achieve reproducible results and could provide a useful tool for routine use by water managers. The SEDEX (sequential extraction method) method, another popular modification, is widely applied in biogeochemical research as it can separate authigenic carbonate fluorapatite from fluorapatite. Other chemical extractions using chelating compounds have attempted to extract P bound with iron and calcium in sediments without disturbing clay-bound or organic P, the purpose being to determine the algal-available non-apatite, apatite and organic fractions of sediment P. All extraction procedures still yield operationally defined fractions and cannot be used for identification of discrete P compounds. Future modifications of the extraction scheme should aim to achieve better extraction efficiency and selectivity, simple handling techniques and methods that can prevent the extracted P from being re-adsorbed onto Fe(OOH) and CaCO3.
学科主题Limnology
URL标识查看原文
WOS关键词NUCLEAR-MAGNETIC-RESONANCE ; FRESH-WATER SEDIMENTS ; LAKE-SEDIMENTS ; MARINE-SEDIMENTS ; INORGANIC PHOSPHATE ; RIVER SEDIMENTS ; OVERLYING WATER ; FRACTIONATION ; SPECIATION ; SOIL
WOS研究方向Marine & Freshwater Biology
语种英语
WOS记录号WOS:000317080300003
资助机构National Natural Science Foundation of China [41006040]; government's Scholarship of Jiangsu Province, China; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
公开日期2013-08-15
源URL[http://ir.yic.ac.cn/handle/133337/6665]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_近岸生态与环境实验室
作者单位1.Nanjing Univ Informat Sci & Technol, Sch Marine Sci, Nanjing 210044, Jiangsu, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China
3.Univ Wollongong, Sch Earth & Environm Sci, Wollongong, NSW 2522, Australia
推荐引用方式
GB/T 7714
Wang, Changyou,Zhang, Yong,Li, Hongli,et al. Sequential extraction procedures for the determination of phosphorus forms in sediment[J]. LIMNOLOGY,2013,14(2):147-157.
APA Wang, Changyou,Zhang, Yong,Li, Hongli,&Morrison, R. John.(2013).Sequential extraction procedures for the determination of phosphorus forms in sediment.LIMNOLOGY,14(2),147-157.
MLA Wang, Changyou,et al."Sequential extraction procedures for the determination of phosphorus forms in sediment".LIMNOLOGY 14.2(2013):147-157.

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来源:烟台海岸带研究所

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