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Chinese Academy of Sciences Institutional Repositories Grid
Experiment and Simulation on Adsorption of 3,5,6-Trichloro-2-Pyridinol in Typical Farmland of Purple Soil, Southwestern China

文献类型:期刊论文

作者Lei, Wenjuan1,2; Zhou, Xiangyang3
刊名SOIL & SEDIMENT CONTAMINATION
出版日期2017
卷号26期号:4页码:345-363
关键词Isothermal Adsorption 3 Breakthrough Curve 5 Simulation 6-trichloro-2-pyridinol Purple Soil
ISSN号1532-0383
DOI10.1080/15320383.2017.1299687
通讯作者Wenjuan Lei
英文摘要The adsorption behaviors of 3,5,6-trichloro-2-pyridinol (TCP) are explored by experiment and simulation on typical farmland of purple soil in southwestern China. Samples are collected from three farmlands with seasonal crop rotation of wheat-corn, rice-rape and vegetables respectively, and isothermal adsorption, breakthrough curves (BTCs) of packed and intact soil column experiments are tested. Adsorption parameters are also obtained by inversion simulation of appropriate model. The results reveal that the adsorption varies substantially in different farmlands and environmental conditions. Isothermal adsorption displays a decrease trend from the soil with crop of wheat-corn to rice-rape, then vegetables, and the main influencing factor is content of clay and silt. Langmuir model fits the isothermal adsorption best (R-2 = 0.99), and the estimated adsorption capacity (q(m)) of soil is 2.73, 1.19 and 0.55 mg/g, corresponding to the sample from farmland of wheat-corn, rice-rape and vegetable, respectively. However, the adsorbed amount by unit mass is almost the same in packed columns because of the incomplete interaction between TCP and soil, accounting for 0.59-3.24% of q(m). In intact soil columns, the adsorption on TCP decreases further, 0.13-1.15% of q(m). Thomas model fits TCP's adsorption well in packed soil columns (R-2 >= 0.97) but poorly in intact soil because of the preferential flow, and the fact that the more intensive the preferential flow, the poorer is the performance of the model.
语种英语
WOS记录号WOS:000417652400001
源URL[http://ir.imde.ac.cn/handle/131551/20720]  
专题成都山地灾害与环境研究所_山地表生过程与生态调控重点实验室
作者单位1.Univ Sichuan, Coll Architecture & Environm, Chengdu 610065, Sichuan, Peoples R China
2.Chinese Acad Sci, Inst Mt Hazards & Environm, Key Lab Mt Surface Proc & Ecol Regulat, Chengdu, Sichuan, Peoples R China
3.Sichuan Univ, State Key Lab Hydraul & Mt River Engn, Chengdu, Sichuan, Peoples R China
推荐引用方式
GB/T 7714
Lei, Wenjuan,Zhou, Xiangyang. Experiment and Simulation on Adsorption of 3,5,6-Trichloro-2-Pyridinol in Typical Farmland of Purple Soil, Southwestern China[J]. SOIL & SEDIMENT CONTAMINATION,2017,26(4):345-363.
APA Lei, Wenjuan,&Zhou, Xiangyang.(2017).Experiment and Simulation on Adsorption of 3,5,6-Trichloro-2-Pyridinol in Typical Farmland of Purple Soil, Southwestern China.SOIL & SEDIMENT CONTAMINATION,26(4),345-363.
MLA Lei, Wenjuan,et al."Experiment and Simulation on Adsorption of 3,5,6-Trichloro-2-Pyridinol in Typical Farmland of Purple Soil, Southwestern China".SOIL & SEDIMENT CONTAMINATION 26.4(2017):345-363.

入库方式: OAI收割

来源:成都山地灾害与环境研究所

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