Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine(III)-CN intermediate
文献类型：期刊论文
| 作者 | Shen, Hang1; Zhang, Xiaohui1; Liu, Qing1; Pan, Jing1; Hu, Wen1; Xiong, Yan1,2; Zhu, Xiangming3 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2015-10-07 |
| 卷号 | 56期号:41页码:5628-5631 |
| 关键词 | Alpha-aminonitriles Cyanation n,N-dialkylanilines Hypervalent Iodine Tmscn |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2015.08.058 |
| 英文摘要 | An environmentally benign and metal-free cyanation method of tertiary amines oxidated by hypervalent iodine(III) intermediate generated in situ from PIFA (or DIB) and TMSCN has been developed. A variety of substituent groups on amines are tolerated to the oxidation of alpha-C-H bond to form C-C bond in the absence of metal catalysts with yields of up to 74%. (C) 2015 Elsevier Ltd. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China[21372265] ; Natural Science Foundation Project of CQ CSTC[cstc2013jcyjA0217] ; Fundamental Research Funds for the Central Universities[CQDXWL-2013-Z012] ; Fundamental Research Funds for the Central Universities[CDJZR14225502] ; Chongqing University Postgraduates' Innovation Project |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000361926100034 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/1931]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 作者单位 | 1.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 3.Natl Univ Ireland Univ Coll Dublin, Sch Chem & Chem Biol, Dublin 4, Ireland |
| 推荐引用方式 GB/T 7714 | Shen, Hang,Zhang, Xiaohui,Liu, Qing,et al. Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine(III)-CN intermediate[J]. TETRAHEDRON LETTERS,2015,56(41):5628-5631. |
| APA | Shen, Hang.,Zhang, Xiaohui.,Liu, Qing.,Pan, Jing.,Hu, Wen.,...&Zhu, Xiangming.(2015).Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine(III)-CN intermediate.TETRAHEDRON LETTERS,56(41),5628-5631. |
| MLA | Shen, Hang,et al."Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine(III)-CN intermediate".TETRAHEDRON LETTERS 56.41(2015):5628-5631. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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