Ethers as hydrogen sources in BF3 center dot OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons
文献类型：期刊论文
| 作者 | Li, Jiaqiang1; Liu, Qing1; Shen, Hang1; Huang, Ruofeng1; Zhang, Xiaohui1; Xiong, Yan1,2; Chen, Changguo1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:104页码:85291-85295 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c5ra14775a |
| 通讯作者 | Xiong, Y (reprint author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China. |
| 英文摘要 | A novel ether/BF3 reductive system has been described, in which diphenylmethanols and their ether and ester derivatives are used as starting materials. Reductions are performed in ether under reflux and an argon atmosphere, and the addition of extra water is beneficial to this reduction. A series of alkanes are able to be prepared with good to excellent yields. A deuterated experiment exhibits that the reductive hydrogen is generated from ether. The mechanism is discussed in detail to explain the observed reactivity. |
| 资助项目 | National Natural Science Foundation of China[21372265] ; National Natural Science Foundation of China[61271059] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000363179900016 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/1972]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Xiong, Yan |
| 作者单位 | 1.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jiaqiang,Liu, Qing,Shen, Hang,et al. Ethers as hydrogen sources in BF3 center dot OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons[J]. RSC ADVANCES,2015,5(104):85291-85295. |
| APA | Li, Jiaqiang.,Liu, Qing.,Shen, Hang.,Huang, Ruofeng.,Zhang, Xiaohui.,...&Chen, Changguo.(2015).Ethers as hydrogen sources in BF3 center dot OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons.RSC ADVANCES,5(104),85291-85295. |
| MLA | Li, Jiaqiang,et al."Ethers as hydrogen sources in BF3 center dot OEt2 promoted reduction of diphenylmethyl alcohols, ethers and esters to hydrocarbons".RSC ADVANCES 5.104(2015):85291-85295. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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