Femtosecond Laser Direct Writing of 3D Silica-like Microstructure from Hybrid Epoxy Cyclohexyl POSS
文献类型：期刊论文
| 作者 | Fang, Gan1 ; Cao, Hongzhong1,2; Cao, Liangcheng1,2; Duan, Xuanming1,2
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| 刊名 | ADVANCED MATERIALS TECHNOLOGIES
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| 出版日期 | 2018-03-01 |
| 卷号 | 3期号:3页码:10 |
| 关键词 | femtosecond laser direct writing polyhedral oligomeric silsesquioxane two-photon polymerization woodpiles |
| ISSN号 | 2365-709X |
| DOI | 10.1002/admt.201700271 |
| 英文摘要 | Given the importance of epoxy cyclohexyl polyhedral oligomeric silsesquioxane (epoxy-POSS) as a silica-like hybrid material of optical clarity, high thermal and mechanic stability, the two-photon initiated polymerization of epoxy-POSS using diphenyliodonium hexafluorophosphate as photoacid generators for UV lithography and femtosecond laser direct writing is studied. The hybrid resist exhibits high thermal stability: decomposition temperatures are found at approximate to 350 and 400 degrees C when calcined in air and argon, respectively. The corresponding calcined products are found as silica-like structures with chemical formulas of C1.5SiO3.5 and C5SiO3, evidenced by energy dispersive X-ray analysis (EDX), fourier-transform infrared spectroscopy (FTIR), and elemental analysis. An equation regarding the two-photon polymerized line width as functions of intensity of laser (P-laser) and scanning speed (V) is proposed in describing the effect of Gaussian light on polymerized lines. Experimental verification of the equation is given to prove a nonlinear optical process. Line width with a resolution of 250 nm is achieved on a glass substrate, while the resolution is 400 nm when fabricated on a silicon wafer. 3D structured woodpiles are fabricated and show no volumetric shrinkage upon 300 degrees C calcination in air environment, demonstrating a high thermal stability. |
| 资助项目 | National Key Research and Development Program of China[2016YFA0200500 (2016YFA0200501)] ; Natural Science Foundation of China (NSFC)[61505208] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000427232800009 |
| 出版者 | WILEY |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/6265]  |
| 专题 | 机器人与3D打印技术创新中心 |
| 通讯作者 | Cao, Liangcheng |
| 作者单位 | 1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Fangzheng Ave 266, Chongqing 400714, Peoples R China 2.Chongqing Key Lab Addit Mfg Technol & Syst, Fangzheng Ave 266, Chongqing 400714, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Gan,Cao, Hongzhong,Cao, Liangcheng,et al. Femtosecond Laser Direct Writing of 3D Silica-like Microstructure from Hybrid Epoxy Cyclohexyl POSS[J]. ADVANCED MATERIALS TECHNOLOGIES,2018,3(3):10. |
| APA | Fang, Gan,Cao, Hongzhong,Cao, Liangcheng,&Duan, Xuanming.(2018).Femtosecond Laser Direct Writing of 3D Silica-like Microstructure from Hybrid Epoxy Cyclohexyl POSS.ADVANCED MATERIALS TECHNOLOGIES,3(3),10. |
| MLA | Fang, Gan,et al."Femtosecond Laser Direct Writing of 3D Silica-like Microstructure from Hybrid Epoxy Cyclohexyl POSS".ADVANCED MATERIALS TECHNOLOGIES 3.3(2018):10. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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