Function of TiO2 Lattice Defects toward Photocatalytic Processes: View of Electronic Driven Force
文献类型：期刊论文
| 作者 | Cui, Huanan1; Liu, Hong1 ; Shi, Jianying1; Wang, Chuan2
|
| 刊名 | INTERNATIONAL JOURNAL OF PHOTOENERGY
 |
| 出版日期 | 2013 |
| 页码 | 16 |
| ISSN号 | 1110-662X |
| DOI | 10.1155/2013/364802 |
| 通讯作者 | Liu, H (reprint author), Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangdong Higher Educ Inst, Key Lab Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China. |
| 英文摘要 | Oxygen vacancies and Ti-related defects (OTDs) are the main lattice defects of TiO2, which have great influence on its photocatalytic activity. To understand the relationship between the defects and photocatalytic activities, detailed discussions based on the electronic driven force provided by these defects are carried out during the three commonly accepted processes in photocatalytic reactions. It is found that these defects inevitably (i) influence the energy structure of the pristine TiO2 as the isolate acceptor/donor level or hybrid with the original orbital, (ii) provide a disordered short-range force that confuses the charge carriers transferring to surface active sites, (iii) act not only as the surface active sites for trapping the charge carriers but also as the main chemisorption sites for O-2, H2O, and organic species. These effects of the defects make them one of the key factors that determine the efficiency of heterogeneous photocatalysis. Clarifying the role of the defects will further facilitate the exploration and the construction of high-performance photocatalysts for practical applications. |
| 资助项目 | Natural Science Foundations of China[21103235] ; Natural Science Foundations of China[21067004] ; Natural Science Foundations of China[51208539] ; Natural Scientific Foundation of Guangdong Province[S2012010010775] ; Science and Technology Plan Projects of Guangdong Province[2010B010900033] ; Science and Technology Programme of Guangzhou City[2013J4100110] ; Key Laboratory of Fuel Cell Technology of Guangdong Province ; Key Laboratory of Environmental Pollution Control and Remediation Technology of Guangdong Province[2011K0011] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Optics ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000329813300001 |
| 出版者 | HINDAWI PUBLISHING CORPORATION |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/600]  |
| 专题 | 水污染过程与治理研究中心 |
| 通讯作者 | Liu, Hong |
| 作者单位 | 1.Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangdong Higher Educ Inst, Key Lab Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 401122, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Huanan,Liu, Hong,Shi, Jianying,et al. Function of TiO2 Lattice Defects toward Photocatalytic Processes: View of Electronic Driven Force[J]. INTERNATIONAL JOURNAL OF PHOTOENERGY,2013:16. |
| APA | Cui, Huanan,Liu, Hong,Shi, Jianying,&Wang, Chuan.(2013).Function of TiO2 Lattice Defects toward Photocatalytic Processes: View of Electronic Driven Force.INTERNATIONAL JOURNAL OF PHOTOENERGY,16. |
| MLA | Cui, Huanan,et al."Function of TiO2 Lattice Defects toward Photocatalytic Processes: View of Electronic Driven Force".INTERNATIONAL JOURNAL OF PHOTOENERGY (2013):16. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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