Dominated Effect Analysis of the Channel Size of Silica Support Materials on the Catalytic Performance of Immobilized Lipase Catalysts in the Transformation of Unrefined Waste Cooking Oil to Biodiesel
文献类型：期刊论文
| 作者 | Zhang, Haidong1; Zou, Yu1; Shen, Yu1,2; Gao, Xue1; Zheng, Xuxu1; Zhang, Xianming1; Chen, Youpeng2; Guo, Jinsong2 |
| 刊名 | BIOENERGY RESEARCH
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 7期号:4页码:1541-1549 |
| 关键词 | Immobilized lipase Channel size Biodiesel Waste cooking oil Mesoporous silica materials |
| ISSN号 | 1939-1234 |
| DOI | 10.1007/s12155-014-9492-y |
| 通讯作者 | Zhang, HD (reprint author), Chongqing Technol & Business Univ, Engn Res Ctr Wasted Oil Recovery Technol, Chinese Minist Educ, Chongqing Key Lab Catalysis Sci & Technol,Sch Env, Chongqing 400067, Peoples R China. |
| 英文摘要 | Three mesoporous silica materials with various channel sizes and structures were employed to prepare immobilized lipase catalysts for the transesterification of unrefined wasted cooking oil (UWCO) to biodiesel at room temperature. The channel size of support material was found to be the key point to obtain high initial specific activity and high sustainability of activity of the immobilized lipase catalysts. A SBA-15 material with appropriate channel size (14.0 nm) demonstrates the best capacity of lipase. The immobilized catalyst with the SBA-15 material shows much higher activity and sustainability of activity than the immobilized catalysts with a MCM-41 material (channel size 1.8 nm) and a mesostructured cellular foam (MCF) material (channel size 28.0 nm) as support materials in the transformation of UWCO to biodiesel. After 60 h of reaction at 28 A degrees C, a fatty acid methyl ester (FAME) yield up to 80.1 and 71.8 % of initial specific activity can be achieved using SBA-15-immobilized lipase. |
| 资助项目 | National Natural Science Foundation of China[NSFC U1362105] ; National Natural Science Foundation of China[21306233] ; Science Research Project of Chongqing Education Commission[KJ130729] ; Science Research Project of Chongqing Education Commission[KJ130702] ; Chongqing Science and Technology Foundation[cstc2013jcyjA50007] ; Chongqing Science and Technology Foundation[cstc2014yykfB90002] ; Chongqing Science and Technology Foundation[jcsf121-2012-02-1] ; Chongqing 100 leading scientists promotion project |
| WOS研究方向 | Energy & Fuels ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000345584500043 |
| 出版者 | SPRINGER |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/1312]  |
| 专题 | 水质生物转化研究中心 |
| 通讯作者 | Zhang, Haidong |
| 作者单位 | 1.Chongqing Technol & Business Univ, Engn Res Ctr Wasted Oil Recovery Technol, Chinese Minist Educ, Chongqing Key Lab Catalysis Sci & Technol,Sch Env, Chongqing 400067, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 401122, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Haidong,Zou, Yu,Shen, Yu,et al. Dominated Effect Analysis of the Channel Size of Silica Support Materials on the Catalytic Performance of Immobilized Lipase Catalysts in the Transformation of Unrefined Waste Cooking Oil to Biodiesel[J]. BIOENERGY RESEARCH,2014,7(4):1541-1549. |
| APA | Zhang, Haidong.,Zou, Yu.,Shen, Yu.,Gao, Xue.,Zheng, Xuxu.,...&Guo, Jinsong.(2014).Dominated Effect Analysis of the Channel Size of Silica Support Materials on the Catalytic Performance of Immobilized Lipase Catalysts in the Transformation of Unrefined Waste Cooking Oil to Biodiesel.BIOENERGY RESEARCH,7(4),1541-1549. |
| MLA | Zhang, Haidong,et al."Dominated Effect Analysis of the Channel Size of Silica Support Materials on the Catalytic Performance of Immobilized Lipase Catalysts in the Transformation of Unrefined Waste Cooking Oil to Biodiesel".BIOENERGY RESEARCH 7.4(2014):1541-1549. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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