Carbon isotopic fractionation during photolysis of hexachlorobenzene
文献类型：期刊论文
| 作者 | Zulin Zhang; Gang Yu; Jie Cheng; Xu Wang; Fusong Zhang; Junliang Zhou |
| 刊名 | PROGRESS IN NATURAL SCIENCE
 |
| 出版日期 | 2005 |
| 卷号 | 15页码:82-88 |
| 关键词 | Hexachlorobenzene Stable Isotope Fractionation Photolysis Isotopic Ratio |
| ISSN号 | 1002-0071 |
| 文献子类 | Article |
| 英文摘要 | The occurrence of carbon isotope fractionation during dechlorination of hexachlorobenzene (HCB) to pentachlorobenzene (penta-CB) has been evaluated under ultraviolet irradiation in a photo-reactor. Stable carbon isotope ratios (delta C-13) of HCB and penta-CB increases from - 27.3 parts per thousand to 18.8 parts per thousand and from - 33.9 parts per thousand to - 19.5 parts per thousand, respectively. The isotopic fractionation of the reactants and products are described with the Rayleigh model, and the following enrichment factors (epsilon) are obtained: - 14.8 parts per thousand for the dechlorination of HCB and 22.7 parts per thousand for the dechlorination product (penta-CB). With the initial delta C-13 value of HCB, this enrichment factor can be used to estimate the fraction (f) of HCB remaining by Rayleigh equation. Strong enrichment of delta C-13 in HCB and penta-CB during photochemical dechlorination might serve as a powerful toot to monitor the photolysis process, such information may provide additional evidence to aid in further understanding the biogeochemical processes of these compounds undergoing in the environment. |
| WOS关键词 | REDUCTIVE DECHLORINATION ; AROMATIC-HYDROCARBONS ; CHLORINATED ETHENES ; PERSISTENT ORGANOCHLORINES ; ANAEROBIC BIODEGRADATION ; MICROBIAL DECHLORINATION ; INTRINSIC BIOREMEDIATION ; TRICHLOROETHENE ; FIELD ; GROUNDWATER |
| WOS研究方向 | Materials Science ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000238034800013 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 源URL | [http://ir.iggcas.ac.cn/handle/132A11/65004]  |
| 专题 | 中国科学院地质与地球物理研究所 |
| 通讯作者 | Zulin Zhang |
| 作者单位 | 1.Tsing Hua Univ, Dept Environm Sci & Engn, POPs Res Ctr, Beijing 100084, Peoples R China 2.Univ Sussex, Sch Life Sci, Dept Biol & Environm Sci, Brighton BN1 9QJ, E Sussex, England 3.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zulin Zhang,Gang Yu,Jie Cheng,et al. Carbon isotopic fractionation during photolysis of hexachlorobenzene[J]. PROGRESS IN NATURAL SCIENCE,2005,15:82-88. |
| APA | Zulin Zhang,Gang Yu,Jie Cheng,Xu Wang,Fusong Zhang,&Junliang Zhou.(2005).Carbon isotopic fractionation during photolysis of hexachlorobenzene.PROGRESS IN NATURAL SCIENCE,15,82-88. |
| MLA | Zulin Zhang,et al."Carbon isotopic fractionation during photolysis of hexachlorobenzene".PROGRESS IN NATURAL SCIENCE 15(2005):82-88. |
入库方式： OAI收割
来源：地质与地球物理研究所
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