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The P,V,T,x properties of binary aqueous chloride solutions up to T=573 K and 100 MPa

文献类型：期刊论文


作者	Mao, Shide 2; Duan, Zhenhao 1
刊名	JOURNAL OF CHEMICAL THERMODYNAMICS
出版日期	2008-07-01
卷号	40 期号:7 页码:1046-1063
关键词	Density P,V,T,x properties Aqueous chloride solutions Apparent molar volume Isochore
ISSN号	0021-9614
DOI	10.1016/j.jct.2008.03.005
文献子类	Review
英文摘要	A highly accurate P,V,T,x model is developed for aqueous chloride solutions of the binary systems, viz. (LiCl + H(2)O), (NaCl + H(2)O), (KCl + H(2)O), (MgCl(2) + H(2)O), (CaCl(2) + H(2)O), (SrCl(2) + H(2)O), and (BaCl(2) + H(2)O). The applied ranges of temperature, pressure, and concentrations for the systems (LiCl + H(2)O), (NaCl + H(2)O), (KCl + H(2)O), (MgCl(2) + H(2)O), (CaCl(2) + H(2)O), (SrCl(2) + H(2)O), and (BaCl(2) + H(2)O) are (273 K to 564 K, 0.1 MPa to 40 MPa, and 0 to 10 molal), (273 K to 573 K. 0.1 MPa to 100 MPa, and 0 to 6.0 molal), (273 K to 543 K, 0.1 MPa to 50 MPa, and 0 to 4.5 molal), (273 K to 543 K, 0.1 MPa to 40 MPa, and 0 to 3.0 molal), 1:273 K to 523 K, 0.1 MPa to 60 MPa, and 0 to 6.0 molal), (298 K to 473 K, 0.1 MPa to 2 MPa, and 0 to 2.0 molal) and (273 K to 473 K, 0.1 MPa to 20 MPa, and 0 to 1.6 molal), respectively. Comparison of the model with thousands of experimental data points concludes that the average deviation over the above T,P,m range is 0.020% to 0.066% in density (or volume) for these systems, which indicates high accuracy. From this model, various volumetric properties, such as the apparent molar volume at infinite dilution and isochores of fluid inclusions, can be calculated, thus having a wide range of geological applications, such as reservoir fluid flow simulation and fluid-inclusion study. A computer code is developed for this model and can be downloaded from the website: www.geochem-model.org/programs.htm and online calculations is made available on: www.geochem-model.org/models.htm (C) 2008 Elsevier Ltd. All rights reserved.
WOS关键词	APPARENT MOLAL VOLUMES ; ALKALINE-EARTH CHLORIDES ; CONCENTRATED ELECTROLYTE MIXTURES ; EQUATION-OF-STATE ; 25 DEGREES C ; THERMODYNAMIC PROPERTIES ; HEAT-CAPACITIES ; SODIUM-CHLORIDE ; ELEVATED-TEMPERATURES ; CALCIUM-CHLORIDE
WOS研究方向	Thermodynamics ; Chemistry
语种	英语
WOS记录号	WOS:000262327300002
出版者	ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
资助机构	National Natural Science Foundation of China(40537032) ; National Natural Science Foundation of China(40537032) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Hengyang Bobang HardAlloy Company Ltd ; Hengyang Bobang HardAlloy Company Ltd ; National Natural Science Foundation of China(40537032) ; National Natural Science Foundation of China(40537032) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Hengyang Bobang HardAlloy Company Ltd ; Hengyang Bobang HardAlloy Company Ltd ; National Natural Science Foundation of China(40537032) ; National Natural Science Foundation of China(40537032) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Hengyang Bobang HardAlloy Company Ltd ; Hengyang Bobang HardAlloy Company Ltd ; National Natural Science Foundation of China(40537032) ; National Natural Science Foundation of China(40537032) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Chinese Academy of Sciences(kzcx2-yw-124) ; Hengyang Bobang HardAlloy Company Ltd ; Hengyang Bobang HardAlloy Company Ltd
源URL	[http://ir.iggcas.ac.cn/handle/132A11/69268]
专题	中国科学院地质与地球物理研究所
通讯作者	Duan, Zhenhao
作者单位	1.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Study Earths Deep Interior, Beijing 100029, Peoples R China 2.China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Mao, Shide,Duan, Zhenhao. The P,V,T,x properties of binary aqueous chloride solutions up to T=573 K and 100 MPa[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2008,40(7):1046-1063.
APA	Mao, Shide,&Duan, Zhenhao.(2008).The P,V,T,x properties of binary aqueous chloride solutions up to T=573 K and 100 MPa.JOURNAL OF CHEMICAL THERMODYNAMICS,40(7),1046-1063.
MLA	Mao, Shide,et al."The P,V,T,x properties of binary aqueous chloride solutions up to T=573 K and 100 MPa".JOURNAL OF CHEMICAL THERMODYNAMICS 40.7(2008):1046-1063.

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来源：地质与地球物理研究所

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The P,V,T,x properties of binary aqueous chloride solutions up to T=573 K and 100 MPa

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