中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Experimental synthesis of the stibnite-antimonselite solid solution series

文献类型:期刊论文

作者Liu, Jiajun1,2,3; Liu, Jianming4; Li, Jiuling5; Xie, Hui1; Wang, Jianping1,2; Deng, Jun1,2; Feng, Caixia1,3; Qi, Feng5; Zhang, Nai6
刊名INTERNATIONAL GEOLOGY REVIEW
出版日期2008-02-01
卷号50期号:2页码:163-176
ISSN号0020-6814
DOI10.2747/0020-6814.50.2.163
文献子类Article
英文摘要Experiments on the Sb-S-Se system were conducted at 300 C, and a continuous stibnite-anti-monselite binary solid solution was established. By substituting S for Se, the compositions of S-rich and Se-rich endmembers were confirmed as Sb2S3 and Sb2Se3, respectively. Based on Se/(S+Se) ratios of microprobe analyses, binary stibnite-antimonselite solid solutions are defined as stibnite, selenium stibnite, sulfur antimonselite, and antimonselite. Microhardness of the stibnite subseries (Sb = 60.11-72.58, S = 13.20-27.63, and Se = 0.00-27.23 wt%) and the antimonselite subseries (Sb = 49.29-59.25, Se = 28.89-51.94, S = 0.00-12.10 wt%) varies from 11.2.95 to 127.72 kg/mm(2). The variation of Se concentration is continuous throughout the series, confirming a random substitution of Se for S. Crystallographic parameters obtained from the series vary as follows: a. = 1.123375-1.163890 nm, b = 1.1.32502-1.179553 nm, c = 0.383914-0.398071 nm, D = 4.593-5.896 g.cm(-3), and V = 0.488425-0.546500 nm(3). As evident from the above data, the higher the Se concentration, the larger the crystallographic parameters. The Sb-S-Se binary solid solutions obey Vegard's law.
WOS关键词CRYSTAL-STRUCTURE
WOS研究方向Geology
语种英语
WOS记录号WOS:000252256300005
出版者BELLWETHER PUBL LTD
源URL[http://ir.iggcas.ac.cn/handle/132A11/69374]  
专题中国科学院地质与地球物理研究所
通讯作者Liu, Jiajun
作者单位1.China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Beijing 100083, Peoples R China
2.China Univ Geosci, Fac Earth Sci, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Geochem, State Key Lab Ore Deposit Geochem, Guiyang 550002, Peoples R China
4.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China
5.Chinese Acad Geol Sci, Inst Mineral Resources, Beijing 100037, Peoples R China
6.Lab Ctr, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Liu, Jiajun,Liu, Jianming,Li, Jiuling,et al. Experimental synthesis of the stibnite-antimonselite solid solution series[J]. INTERNATIONAL GEOLOGY REVIEW,2008,50(2):163-176.
APA Liu, Jiajun.,Liu, Jianming.,Li, Jiuling.,Xie, Hui.,Wang, Jianping.,...&Zhang, Nai.(2008).Experimental synthesis of the stibnite-antimonselite solid solution series.INTERNATIONAL GEOLOGY REVIEW,50(2),163-176.
MLA Liu, Jiajun,et al."Experimental synthesis of the stibnite-antimonselite solid solution series".INTERNATIONAL GEOLOGY REVIEW 50.2(2008):163-176.

入库方式: OAI收割

来源:地质与地球物理研究所

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