中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electron microprobe analyses of altered Th-rich britholite-(Ce) from the Saima alkali complex, North China

文献类型:期刊论文

作者Yang, ZM; Smith, M; Henderson, P; Le Bas, MJ; Tao, KJ; Zhang, PS
刊名NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE
出版日期1999-10-01
期号10页码:453-467
关键词britholite REE-Ca-Th chemical composition zoning pattern
ISSN号0028-3649
文献子类Article
英文摘要The Ca-rich analogue of britholite-(Ce) (fenghuanglite) from melanite-urtite of the Saima alkali complex, Liaoning Province, China, was reinvestigated by electron microprobe analyses. Two alteration patterns were observed: a spotted zoning and continuous zoning. Weight loss due to metamictisation ranges from 7 to 11 wt.%. The thorium content is unusually high ranging from 5.80 to 26.19 %. In the continuous zoning samples SiO2 and ThO2 are high, and PO4, CaO and REE2O3 are low relative to the spotted zoning samples. The content of Ca shows a negative correlation with Th. From the spotted zoning samples to the continuous zoning samples A-site vacancies and fourvalent cations increase, divalent and trivalent cations decrease, X-site vacancies increase, and F and O decrease. The main changes in britholite during the alteration processes can be described as: 2P(5+) + 2REE(3+) + 4Ca(2+) = 2Si(4+) + 4Th(4+) + 2 square 3.3 H+ + 7.2H(2)O + (A(10)Si(5.2)P(0.6)Ti(0.1)Al(0.1)O(24)F(2))(bss) = 1.9A(aq) + 0.7HF(aq) + (A(8.1)Si(5.2)P(0.6)Ti(0.1)Al(0.1)O(22.7)F(1.3). 8.5H(2)O)(bss) The species previously identified as "fenghuanglite" is proved to be a britholite solid solution series involving (REE, Ca, Th). In this series most samples are characterized by the: predominant REE atoms and can be determined as Th-rich britholite -(Ce).
WOS关键词PYROCHLORE GROUP MINERALS ; GEOCHEMICAL ALTERATION ; CRYSTAL-STRUCTURES ; SUBGROUP
WOS研究方向Mineralogy
语种英语
WOS记录号WOS:000083607600002
出版者E SCHWEIZERBARTSCHE VERLAGS
源URL[http://ir.iggcas.ac.cn/handle/132A11/75368]  
专题中国科学院地质与地球物理研究所
通讯作者Yang, ZM
作者单位1.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China
2.Nat Hist Museum, Dept Mineral, London SW7 5BD, England
3.Univ Southampton, Dept Geol, Southampton Oceanog Ctr, Southampton SO14 3ZH, Hants, England
推荐引用方式
GB/T 7714
Yang, ZM,Smith, M,Henderson, P,et al. Electron microprobe analyses of altered Th-rich britholite-(Ce) from the Saima alkali complex, North China[J]. NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE,1999(10):453-467.
APA Yang, ZM,Smith, M,Henderson, P,Le Bas, MJ,Tao, KJ,&Zhang, PS.(1999).Electron microprobe analyses of altered Th-rich britholite-(Ce) from the Saima alkali complex, North China.NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE(10),453-467.
MLA Yang, ZM,et al."Electron microprobe analyses of altered Th-rich britholite-(Ce) from the Saima alkali complex, North China".NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE .10(1999):453-467.

入库方式: OAI收割

来源:地质与地球物理研究所

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