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An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar
文献类型:期刊论文
作者 | Duan, ZH; Sun, R |
刊名 | CHEMICAL GEOLOGY
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出版日期 | 2003-02-14 |
卷号 | 193期号:3-4页码:257-271 |
关键词 | CO2 solubility CO2 thermodynamics specific interaction modeling aqueous CO2 solution solubility model equation of state |
ISSN号 | 0009-2541 |
文献子类 | Article |
英文摘要 | A thermodynamic model for the solubility of carbon dioxide (CO2) in pure water and in aqueous NaCl solutions for temperatures from 273 to 533 K, for pressures from 0 to 2000 bar, and for ionic strength from 0 to 4.3 m is presented. The model is based on a specific particle interaction theory for the liquid phase and a highly accurate equation of state for the vapor phase. With this specific interaction approach, this model is able to predict CO2 solubility in other systems, such as CO2-H2O-CaCl2 and CO2-seawater, without fitting experimental data from these systems. Comparison of the model predictions with experimental data indicates that the model is within or close to experimental uncertainty, which is about 7% in CO2 solubility. (C) 2003 Elsevier Science B.V. All rights reserved. |
WOS关键词 | CARBON-DIOXIDE ; SODIUM-CHLORIDE ; NATURAL-WATERS ; IONIC-STRENGTH ; PREDICTION ; SYSTEM ; THERMODYNAMICS ; PRESSURE ; EQUATION ; STATE |
WOS研究方向 | Geochemistry & Geophysics |
语种 | 英语 |
WOS记录号 | WOS:000180816500007 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iggcas.ac.cn/handle/132A11/79115] ![]() |
专题 | 中国科学院地质与地球物理研究所 |
通讯作者 | Duan, ZH |
作者单位 | 1.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China 2.Univ Calif San Diego, Dept Chem, La Jolla, CA 92129 USA 3.China Univ Geosci, Fac Earth Resources, Wuhan 430074, Peoples R China |
推荐引用方式 GB/T 7714 | Duan, ZH,Sun, R. An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar[J]. CHEMICAL GEOLOGY,2003,193(3-4):257-271. |
APA | Duan, ZH,&Sun, R.(2003).An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar.CHEMICAL GEOLOGY,193(3-4),257-271. |
MLA | Duan, ZH,et al."An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar".CHEMICAL GEOLOGY 193.3-4(2003):257-271. |
入库方式: OAI收割
来源:地质与地球物理研究所
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