Ore Genesis of the Kalatongke Cu-Ni Sulfide Deposits, Western China: Constraints from Volatile Chemical and Carbon Isotopic Compositions
文献类型:期刊论文
作者 | Fu Piaoer1; Tang Qingyan1; Zhang Mingjie1; Zhang Zhaowei2; Li Liwu3; Li Wenyuan2 |
刊名 | ACTA GEOLOGICA SINICA-ENGLISH EDITION
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出版日期 | 2012-06-01 |
卷号 | 86期号:3页码:568-578 |
关键词 | Ore genesis chemical composition carbon isotope volatile mafic-ultramafic intrusion Kalatongke Cu-Ni sulfide deposits Xinjiang |
ISSN号 | 1000-9515 |
DOI | 10.1111/j.1755-6724.2012.00686.x |
文献子类 | Article |
英文摘要 | The Kalatongke CuNi sulfide deposits located in the East Junggar terrane, northern Xinjiang, western China are the largest magmatic sulfide deposits in the Central Asian Orogenic Belt (CAOB). The chemical and carbon isotopic compositions of the volatiles trapped in olivine, pyroxene and sulfide mineral separates were analyzed by vacuum stepwise-heating mass spectrometry. The results show that the released volatiles are concentrated at three temperature intervals of 200-400 degrees C, 400-900 degrees C and 900-1200 degrees C. The released volatiles from silicate mineral separates at 400-900 degrees C and 900-1200 degrees C have similar chemical and carbon isotopic compositions, which are mainly composed of H2O (av. similar to 92 mol%) with minor H2, CO2, H2S and SO2, and they are likely associated with the ore-forming magmatic volatiles. Light d13CCO2 values (from 20.86 parts per thousand to 12.85 parts per thousand) of pyroxene indicate crustal contamination occurred prior to or synchronous with pyroxene crystallization of mantle-derived ore-forming magma. The elevated contents of H2 and H2O in the olivine and pyroxene suggest a deep mantle-originated ore-forming volatile mixed with aqueous volatiles from recycled subducted slab. High contents of CO2 in the ore-forming magma volatiles led to an increase in oxygen fugacity, and thereby reduced the solubility of sulfur in the magma, then triggered sulfur saturation followed by sulfide melt segregation; CO2 contents correlated with Cu contents in the whole rocks suggest that a supercritical state of CO2 in the ore-forming magma system under high temperature and pressure conditions might play a key role in the assemblage of huge Cu and Ni elements. The volatiles released from constituent minerals of intrusion 1* have more CO2 and SO2 oxidized gases, higher CO2/CH4 and SO2/H2S ratios and lighter d13CCO2 than those of intrusions 2# and 3#. This combination suggests that the higher oxidation state of the volatiles in intrusion 1# than intrusions 2# and 3#, which could be one of key ore-forming factors for large amounts of ores and high contents of Cu and Ni in intrusion 1#. The volatiles released at 200-400 degrees C are dominated by H2O with minor CO2, N2+CO and SO2, with d13CCO2, values (25.66 parts per thousand to 22.98 parts per thousand) within the crustal ranges, and are considered to be related to secondary tectonic hydrothermal activities. |
WOS关键词 | MAFIC-ULTRAMAFIC INTRUSIONS ; NW CHINA ; NORTHERN XINJIANG ; PRINCIPAL CHARACTERISTICS ; GEODYNAMIC IMPLICATIONS ; ALTAY OROGENS ; FLOOD BASALTS ; MANTLE PLUME ; GEOCHEMISTRY ; EVOLUTION |
WOS研究方向 | Geology |
语种 | 英语 |
WOS记录号 | WOS:000306065300005 |
出版者 | WILEY-BLACKWELL |
资助机构 | NSF of China(41072056 ; NSF of China(41072056 ; Key Projects of China Geological Survey(1212011121092) ; Key Projects of China Geological Survey(1212011121092) ; MOE(311010) ; MOE(311010) ; 40772058 ; 40772058 ; 91014003 ; 91014003 ; 40534020 ; 40534020 ; 40772062) ; 40772062) ; NSF of China(41072056 ; NSF of China(41072056 ; Key Projects of China Geological Survey(1212011121092) ; Key Projects of China Geological Survey(1212011121092) ; MOE(311010) ; MOE(311010) ; 40772058 ; 40772058 ; 91014003 ; 91014003 ; 40534020 ; 40534020 ; 40772062) ; 40772062) ; NSF of China(41072056 ; NSF of China(41072056 ; Key Projects of China Geological Survey(1212011121092) ; Key Projects of China Geological Survey(1212011121092) ; MOE(311010) ; MOE(311010) ; 40772058 ; 40772058 ; 91014003 ; 91014003 ; 40534020 ; 40534020 ; 40772062) ; 40772062) ; NSF of China(41072056 ; NSF of China(41072056 ; Key Projects of China Geological Survey(1212011121092) ; Key Projects of China Geological Survey(1212011121092) ; MOE(311010) ; MOE(311010) ; 40772058 ; 40772058 ; 91014003 ; 91014003 ; 40534020 ; 40534020 ; 40772062) ; 40772062) |
源URL | [http://ir.iggcas.ac.cn/handle/132A11/84426] ![]() |
专题 | 中国科学院地质与地球物理研究所 |
通讯作者 | Zhang Mingjie |
作者单位 | 1.Lanzhou Univ, Sch Earth Sci, Key Lab Western Chinas Environm Syst MOE, Lanzhou 730000, Peoples R China 2.CGS, Xian Inst Geol & Mineral Resources, Xian 710054, Peoples R China 3.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Petr Resource Res, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Fu Piaoer,Tang Qingyan,Zhang Mingjie,et al. Ore Genesis of the Kalatongke Cu-Ni Sulfide Deposits, Western China: Constraints from Volatile Chemical and Carbon Isotopic Compositions[J]. ACTA GEOLOGICA SINICA-ENGLISH EDITION,2012,86(3):568-578. |
APA | Fu Piaoer,Tang Qingyan,Zhang Mingjie,Zhang Zhaowei,Li Liwu,&Li Wenyuan.(2012).Ore Genesis of the Kalatongke Cu-Ni Sulfide Deposits, Western China: Constraints from Volatile Chemical and Carbon Isotopic Compositions.ACTA GEOLOGICA SINICA-ENGLISH EDITION,86(3),568-578. |
MLA | Fu Piaoer,et al."Ore Genesis of the Kalatongke Cu-Ni Sulfide Deposits, Western China: Constraints from Volatile Chemical and Carbon Isotopic Compositions".ACTA GEOLOGICA SINICA-ENGLISH EDITION 86.3(2012):568-578. |
入库方式: OAI收割
来源:地质与地球物理研究所
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