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Chinese Academy of Sciences Institutional Repositories Grid
Soil formation and mineralogy of a Rhodic Luvisol - insights from magnetic and geochemical studies

文献类型:期刊论文

作者Jordanova, Neli1; Jordanova, Diana1; Liu, Qingsong2; Hu, Pengxiang2; Petrov, Petar1; Petrovsky, Eduard3
刊名GLOBAL AND PLANETARY CHANGE
出版日期2013-11-01
卷号110页码:397-413
ISSN号0921-8181
关键词red soil magnetism hematite goethite pedogenesis REE Sahara dust
DOI10.1016/j.gloplacha.2013.08.020
文献子类Article
英文摘要Relict terra rossa soil from the most south-eastern part of Bulgaria, characterized by transitional Mediterranean climate, has been comprehensively studied by integrating magnetic, geochemical and spectroscopic methods to reveal the origin, pedogenic processes and phases in soil development of this particular soil type. The red colored Rhodic Luvisol is developed on metamorphosed Triassic limestones. Magnetic methods, which include thermomagnetic analysis of susceptibility, isothermal remanent magnetization (IRM) acquisition and thermal demagnetization. IRM component analysis, hysteresis measurements, low-temperature (down to 10 K) IRM behavior, anhysteretic remanence and frequency dependent susceptibility, indicate the presence of three major magnetic phases maghemite, hematite (Hm) and goethite (Gt). Hematite and goethite are identified also by diffuse reflectance spectroscopy (DRS). Depth variations of the ratio Hm/(Hm + Gt), deduced from the DRS spectra show higher hematite content in the upper soil horizons (A + B), while goethite's contribution is enriched in the lowermost part of the profile. A similar ratio, based on the established magnetic proxies for hematite and goethite, was constructed and its variations were compared with the DRS data. The magnetic proxy for Hm/(Hm + Gt) reflects the variations in the remanence-carrying mineral fraction of hematite and goethite and the obtained difference with the DRS data are ascribed to the presence of the paramagnetic (or superparamagnetic) goethite in the A and illuvial B-t1 and B-t2 horizons. The low ratio Fe-o/Fe-d between dithionite (Fe-d)- and oxalate (Fe-o)-extractable iron, and the large proportion of extractable iron with respect to total iron (Fe-d/Fe-tot) indicate an advanced degree of weathering. Depth variations of magnetic parameters and ratios (chi(lf), chi(fd), S-ratio) suggest magnetic enhancement with SP-SD maghemite grains, accompanied by magnetically stable magnetic carriers in the soil, while the parent material is magnetically depleted. Based on grain-size variations of the pedogenic maghemite phase, deduced from a chi(ARM) VS. chi(fd) plot, and variations in the content of hematite and goethite in depth, in the uppermost part of the profile, aging of the pedogenic iron oxides is assumed (grain growth from SP to SD and larger), while in the bottom part of B-t1 and the B-t2, changes only in the concentration of maghemite are inferred. The presence of goethite in different parts of the profile and the mineralogy of Fe-Mn nodules are linked to more recent (Holocene) pedogenic changes in the profile. Analyses of trace and rare earth element content and magnetic data suggest possible contributions of aeolian dust flux from Sahara during the soil formation. (C) 2013 Elsevier BY. All rights reserved.
WOS关键词IRON-OXIDE MINERALOGY ; TERRA-ROSSA ; GRAIN-SIZE ; XERALF CHRONOSEQUENCE ; MEDITERRANEAN REGION ; NORTHWESTERN SPAIN ; ROOM-TEMPERATURE ; CANARY-ISLANDS ; SAHARAN DUST ; AFRICAN DUST
WOS研究方向Physical Geography ; Geology
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000329333400013
源URL[http://ir.iggcas.ac.cn/handle/132A11/87578]  
专题中国科学院地质与地球物理研究所
通讯作者Jordanova, Neli
作者单位1.Bulgarian Acad Sci, Natl Inst Geophys Geodesy & Geog, Sofia, Bulgaria
2.Chinese Acad Sci, Inst Geol & Geophys, Beijing, Peoples R China
3.Acad Sci Czech Republic, Inst Geophys, Prague, Czech Republic
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Jordanova, Neli,Jordanova, Diana,Liu, Qingsong,et al. Soil formation and mineralogy of a Rhodic Luvisol - insights from magnetic and geochemical studies[J]. GLOBAL AND PLANETARY CHANGE,2013,110:397-413.
APA Jordanova, Neli,Jordanova, Diana,Liu, Qingsong,Hu, Pengxiang,Petrov, Petar,&Petrovsky, Eduard.(2013).Soil formation and mineralogy of a Rhodic Luvisol - insights from magnetic and geochemical studies.GLOBAL AND PLANETARY CHANGE,110,397-413.
MLA Jordanova, Neli,et al."Soil formation and mineralogy of a Rhodic Luvisol - insights from magnetic and geochemical studies".GLOBAL AND PLANETARY CHANGE 110(2013):397-413.

入库方式: OAI收割

来源:地质与地球物理研究所

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