中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formationA state of the art scrutiny

文献类型:期刊论文

作者El Goresy, A.1; Lin, Y.2; Miyahara, M.3; Gannoun, A.4; Boyet, M.4; Ohtani, E.5; Gillet, P.6; Trieloff, M.7; Simionovici, A.8; Feng, L.2
刊名METEORITICS & PLANETARY SCIENCE
出版日期2017-05-01
卷号52期号:5页码:781-806
ISSN号1086-9379
DOI10.1111/maps.12832
文献子类Article
英文摘要Mineral inventories of enstatite chondrites; (EH and EL) are strictly dictated by combined parameters mainly very low dual oxygen (fO(2)) and sulfur (fS(2)) fugacities. They are best preserved in the Almahata Sitta MS-17, MS-177 fragments, and the ALHA 77295 and MAC 88136 Antarctic meteorites. These conditions induce a stark change of the geochemical behavior of nominally lithophile elements to chalcophile or even siderophile and changes in the elemental partitioning thus leading to formation of unusual mineral assemblages with high abundance of exotic sulfide species and enrichment in the metallic alloys, for example, silicides and phosphides. Origin and mode of formation of these exotic chondrites, and their parental source regions could be best scrutinized by multitask research experiments of the most primitive members covering mineralogical, petrological, cosmochemical, and indispensably short-lived isotopic chronology. The magnitude of temperature and pressure prevailed during their formation in their source regions could eventually be reasonably estimated: pre- and postaccretionary could eventually be deduced. The dual low fugacities are regulated by the carbon to oxygen ratios estimated to be >0.83 and <1.03. These parameters not only induce unusual geochemical behavior of the elements inverting many nominally lithophile elements to chalcophile or even siderophile or anthracophile. Structure and mineral inventories in EL3 and EH3 chondrites are fundamentally different. Yet EH3 and EL3 members store crucial information relevant to eventual source regions and importantly possible variation in C/O ratio in the course of their evolution. EL3 and EH3 chondrites contain trichotomous lithologies (1) chondrules and their fragments, (2) polygonal enstatite-dominated objects, and (3) multiphase metal-rich nodules. Mineralogical and cosmochemical inventories of lithologies in the same EL3 indicate not only similarities (REE inventory and anomalies in oldhamite) but also distinct differences (sinoite-enstatite-graphite relationship). Oldhamite in chondrules and polygonal fragments in EL3 depict negative Eu anomaly attesting a common cosmochemical source. Metal-dominated nodules in both EL3 and EH3 are conglomerates of metal clasts and sulfide fragments in EH3 and concentrically zoned C-bearing metal micropebbles (25m 50m) in EL3 thus manifesting a frozen in unique primordial accretionary metal texture and composition. Sinoite-enstatite-diopside-graphite textures reveal a nucleation and growth strongly suggestive of fluctuating C/O ratio during their nucleation and growth in the source regions. Mineral inventories, sulfide phase relations, sinoite-enstatite-graphite intergrowth, carbon and nitrogen isotopic compositions of graphite, spatial nitrogen abundance in graphite in metal nodules, and last but not least I-129/Xe-129 and Mn-53/Cr-53 systematics negate any previously suggested melting episode, pre-accretionary or dynamic, in parental asteroids.
WOS关键词UNEQUILIBRATED ENSTATITE CHONDRITES ; THERMAL HISTORIES ; EH-CHONDRITES ; OLDHAMITE ; SITTA ; NININGERITE ; CHONDRULES ; CHEMISTRY ; MATRIX ; CARBON
WOS研究方向Geochemistry & Geophysics
语种英语
WOS记录号WOS:000401720000001
出版者WILEY
资助机构Natural Science Foundation of China(41273077 ; Ecole Polytechnique Federale de Lausanne, Switzerland ; Klaus Tschira Stiftung ; 41521062) ; Natural Science Foundation of China(41273077 ; Ecole Polytechnique Federale de Lausanne, Switzerland ; Klaus Tschira Stiftung ; 41521062) ; Natural Science Foundation of China(41273077 ; Ecole Polytechnique Federale de Lausanne, Switzerland ; Klaus Tschira Stiftung ; 41521062) ; Natural Science Foundation of China(41273077 ; Ecole Polytechnique Federale de Lausanne, Switzerland ; Klaus Tschira Stiftung ; 41521062)
源URL[http://ir.iggcas.ac.cn/handle/132A11/52930]  
专题地质与地球物理研究所_中国科学院地球与行星物理重点实验室
通讯作者El Goresy, A.
作者单位1.Univ Bayreuth, Bayer Geoinst, D-95447 Bayreuth, Germany
2.Chinese Acad Sci, Key Lab Earth & Planetary Phys, Inst Geol & Geophys, Beijing, Peoples R China
3.Hiroshima Univ, Dept Earth & Planetary Syst Sci, Grad Sch Sci, Higashihiroshima 7398526, Japan
4.CNRS, UMR 6524, LMV, F-63038 Clermont Ferrand, France
5.Tohoku Univ, Dept Earth Sci, Grad Sch Sci, Sendai, Miyagi 9808578, Japan
6.Ecole Polytech Fed Lausanne, CH-1015 Lausanne, Switzerland
7.Heidelberg Univ, Klaus Tschira Lab Kosmochem, Inst Geowissensch, D-69126 Heidelberg, Germany
8.Univ Grenoble, UGA CNRS, ISTerre, Observ Sci, CS 40700, F-38058 Grenoble 9, France
9.Ecole Normale Super Lyon, LGL TPE, CNRS, UMR 5570, F-69364 Lyon, France
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GB/T 7714
El Goresy, A.,Lin, Y.,Miyahara, M.,et al. Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formationA state of the art scrutiny[J]. METEORITICS & PLANETARY SCIENCE,2017,52(5):781-806.
APA El Goresy, A..,Lin, Y..,Miyahara, M..,Gannoun, A..,Boyet, M..,...&Lemelle, L..(2017).Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formationA state of the art scrutiny.METEORITICS & PLANETARY SCIENCE,52(5),781-806.
MLA El Goresy, A.,et al."Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formationA state of the art scrutiny".METEORITICS & PLANETARY SCIENCE 52.5(2017):781-806.

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来源:地质与地球物理研究所

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