中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The Isotopic Tracer and Resource Value of Microbial Gas Production in Coalbeds-A Case Study of Coalbed Gas in Enhong, China

文献类型:期刊论文

作者Tao, Mingxin1; Ma, Yuzhen1; Li, Zhongping2; Li, Jing1; Liu, Pengyang1; Wang, Yanlong3; Chen, Xiangrui1; Zhang, Aihua1
刊名ENERGY & FUELS
出版日期2015-04-01
卷号29期号:4页码:2134-2142
DOI10.1021/ef502565g
文献子类Article
英文摘要From the new perspective of the dynamic isotopic fractionation of microbes and the mixture of secondary biogenic gas and thermogenic gas in coalbeds, this study evaluates the geochemical characteristics of mixed coalbed gas in Enhong. Additionally, by using isotopes, the study traces the microbial activities and the results of those activities, such as the methane production of bacteria, and reveals the formation mechanism and genetic types of coalbed gas. The measured delta C-13(1) values of the coalbed gas samples are from -54.5 parts per thousand to -32.0 parts per thousand. Based on the values of Ro and delta C-13(2), by calculation, the delta C-13(1) values of thermogenic methane range from -30.6 parts per thousand to -28.1 parts per thousand and from -30.7 parts per thousand to -28.3 parts per thousand, respectively. The results of the two calculations are highly consistent, and both are approximately 20 parts per thousand higher than the measured values. The measured delta DCH4 values are from -217 parts per thousand to -196 parts per thousand, being between thermogenic methane and microbiogenic methane; the delta(13)CCO2 values are from -30.5 parts per thousand to -23.9 parts per thousand, growing heavier with respect to the original thermogenic gas; the measured delta C-13(2) values are from -25.7 parts per thousand to -22.6 parts per thousand, and the estimated delta C-13(2) values are from -21.8 parts per thousand to -21.2 parts per thousand, also indicating growing heavier. The delta C-13(1) and delta C-13(2) values are negatively correlated; both the Delta delta(CC2)-C-13-C-1 and Delta delta(13)CCO2-C-1 values are increasing. All of the above characteristics indicate that CO2 is reduced into microbial genetic methane by methane-producing bacteria and it mixes with thermogenic gas, which is new evidence showing the existence of secondary biogenic gas. Via calculations using a variety of data, such as the values of delta C-13(1), delta C-13(2) and Ro, it is found that thermogenic methane accounts for approximately 38% to 58% of the total amount, and microbial genetic methane accounts for approximately 42% to 62%. The proportion of micro-biogenic methane reduced from the top down, which occupied more than 50% of that in the coalbed buried within 1000 m deep. It increased the content of coalbed gas by more than 1 times. Within 1000 m deep, coalbed temperatures are generally lower than 40 degrees C, which is the most appropriate section for methanogenic bacteria activity and secondary biogenic gas generation. Coalbed uplift to the shallow parts in the late stage is the basic geological condition for the formation of secondary biogenic gas, which has significant resource value.
WOS关键词RATIO MASS-SPECTROMETRY ; NATURAL-GAS ; ORIGIN ; METHANE ; CARBON ; BASIN ; GEOCHEMISTRY ; YUNNAN ; TEMPERATURE ; COALFIELD
WOS研究方向Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000353251800010
资助机构National Natural Science Foundation of China(41472102 ; National Natural Science Foundation of China(41472102 ; 41172107) ; 41172107) ; National Natural Science Foundation of China(41472102 ; National Natural Science Foundation of China(41472102 ; 41172107) ; 41172107)
源URL[http://ir.iggcas.ac.cn/handle/132A11/62601]  
专题地质与地球物理研究所_兰州油气中心
作者单位1.Beijing Normal Univ, Minist Educ, Key Lab Environm Change & Nat Disaster, Coll Resources Sci & Technol, Beijing 100875, Peoples R China
2.Chinese Acad Sci, Inst Geol & Geophys, Lanzhou Petr Resources Res Ctr, Lanzhou 730000, Peoples R China
3.CCTEG, Xian Res Inst, Xian 710054, Peoples R China
推荐引用方式
GB/T 7714
Tao, Mingxin,Ma, Yuzhen,Li, Zhongping,et al. The Isotopic Tracer and Resource Value of Microbial Gas Production in Coalbeds-A Case Study of Coalbed Gas in Enhong, China[J]. ENERGY & FUELS,2015,29(4):2134-2142.
APA Tao, Mingxin.,Ma, Yuzhen.,Li, Zhongping.,Li, Jing.,Liu, Pengyang.,...&Zhang, Aihua.(2015).The Isotopic Tracer and Resource Value of Microbial Gas Production in Coalbeds-A Case Study of Coalbed Gas in Enhong, China.ENERGY & FUELS,29(4),2134-2142.
MLA Tao, Mingxin,et al."The Isotopic Tracer and Resource Value of Microbial Gas Production in Coalbeds-A Case Study of Coalbed Gas in Enhong, China".ENERGY & FUELS 29.4(2015):2134-2142.

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来源:地质与地球物理研究所

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