中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature

文献类型:期刊论文

作者Li, Ping1; Wu, Hanyu1,3; Liang, Jianjun1; Yin, Zhuoxin3; Pan, Duoqiang3; Fan, Qiaohui1; Xu, Di2; Wu, Wangsuo3
刊名RADIOCHIMICA ACTA
出版日期2017-12-01
卷号105期号:12页码:1049-1058
关键词Feldspar Eu(Iii) Sorption Humic Acid Xps
ISSN号0033-8230
DOI10.1515/ract-2017-2797
文献子类Article
英文摘要The sorption of Eu(III) on potassium feldspar (K-feldspar) was studied under various physicochemical conditions such as pH, temperature, counter ions and organic matter. The results showed that the sorption of Eu(III) on K-feldspar significantly increased with the increase of pH, and high Eu(III) concentration can inhibit such immobility to some extent. The presence of humic acid (HA) can increase the sorption of Eu(III) on K-feldspar in low pH range; while inhibit to a large extent under alkaline conditions. It is very interesting that at pH similar to 6.5, high ionic strength can promote the sorption of Eu(III) on K-feldspar in the presence of HA. In contrast, Eu(III) sorption was restricted obviously by NaCl in the absence of HA. The sorption procedure was involved with ion exchange and/or outer-sphere complexation as well as inner-sphere complexation. The presence of F-and PO43- dramatically enhanced Eu(III) sorption on K-feldspar, whereas both SO42- and CO32- had negative effects on Eu(III) sorption. X-ray photoelectron spectroscopy analysis indicated that Eu(III) tended to form hydrolysates at high initial concentration (3 x 10(-4) mol/L) and high temperature (338 K).
WOS关键词COMPETITIVE ADSORPTION ; AQUEOUS-SOLUTIONS ; HUMIC SUBSTANCES ; COMBINED BATCH ; FOREIGN IONS ; FULVIC-ACID ; METAL-IONS ; STRENGTH ; BENTONITE ; EXAFS
WOS研究方向Chemistry ; Nuclear Science & Technology
语种英语
WOS记录号WOS:000416374300008
出版者WALTER DE GRUYTER GMBH
资助机构National Natural Science Foundation of China(21601169 ; "100-Talent" program from Chinese Academy of Science in Lanzhou Center for Oil & Gas Resources, Institute of Geology and Geophysics, CAS "Light of West China" Program ; Key Laboratory of Special Function Materials and Structure Design, Ministry of Education ; 41573128 ; 21601179) ; National Natural Science Foundation of China(21601169 ; "100-Talent" program from Chinese Academy of Science in Lanzhou Center for Oil & Gas Resources, Institute of Geology and Geophysics, CAS "Light of West China" Program ; Key Laboratory of Special Function Materials and Structure Design, Ministry of Education ; 41573128 ; 21601179) ; National Natural Science Foundation of China(21601169 ; "100-Talent" program from Chinese Academy of Science in Lanzhou Center for Oil & Gas Resources, Institute of Geology and Geophysics, CAS "Light of West China" Program ; Key Laboratory of Special Function Materials and Structure Design, Ministry of Education ; 41573128 ; 21601179) ; National Natural Science Foundation of China(21601169 ; "100-Talent" program from Chinese Academy of Science in Lanzhou Center for Oil & Gas Resources, Institute of Geology and Geophysics, CAS "Light of West China" Program ; Key Laboratory of Special Function Materials and Structure Design, Ministry of Education ; 41573128 ; 21601179)
源URL[http://ir.iggcas.ac.cn/handle/132A11/62673]  
专题地质与地球物理研究所_兰州油气中心
通讯作者Fan, Qiaohui; Xu, Di
作者单位1.Chinese Acad Sci, Inst Geol & Geophys, CAS Key Lab Petr Resources Res, Key Lab Petr Resources, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, Nanjing Inst Geog & Limnol, State Key Lab Lake Sci & Environm, Nanjing 210008, Jiangsu, Peoples R China
3.Lanzhou Univ, Sch Nucl Sci & Technol, Radiochem Lab, Lanzhou 730000, Gansu, Peoples R China
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Li, Ping,Wu, Hanyu,Liang, Jianjun,et al. Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature[J]. RADIOCHIMICA ACTA,2017,105(12):1049-1058.
APA Li, Ping.,Wu, Hanyu.,Liang, Jianjun.,Yin, Zhuoxin.,Pan, Duoqiang.,...&Wu, Wangsuo.(2017).Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature.RADIOCHIMICA ACTA,105(12),1049-1058.
MLA Li, Ping,et al."Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature".RADIOCHIMICA ACTA 105.12(2017):1049-1058.

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来源:地质与地球物理研究所

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